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	Co-crystallization of resorcin[4]arene tetracarboxylic acid with triethylamine: synthesis and crystal structure
	Zou Qing-Zhu1,2; Chen Jian-Shan1; Fu Rui-Biao1; Hu Sheng-Min1; Sheng Tian-Lu1; Wang Xin1,2; Shen Chao-Jun1,2; Chen Dong-Bo1,2; Wu Xin-Tao1
刊名	Chinese journal of structural chemistry
	2010
卷号	29期号:1页码:114-120
关键词	Resorcinarenes Crystal structure Supramolecular chemistry Carboxylic acid derivations
ISSN号	0254-5861
通讯作者	Wu xin-tao(wxt@fjirsm.ac.cn)
英文摘要	Treatment of resorcin[4]arene tetracarboxylic acid 1 with triethylamine in the presence of co(ch(3)coo)(2)center dot 4h(2)o and 4,4'-bipyridine gave a co-crystallization 1(4-)center dot 4et(3)nh(+) (c(32)h(20)o(16)(4-)center dot 4et(3)nh(+), m(r) = 1069.27) from ethanol and water. the compound was structurally determined by single-crystal x-ray diffraction. the crystal belongs to monoclinic, space group p2(1)/n, with a = 8.1763(18), b = 12.913(3), c =28.724(7) angstrom, beta = 97.574(4)degrees, v = 3006.3(12) angstrom(3), z = 2, d(c) = 1.181 g/cm(3), f(000) = 1152, r(int) = 0.0275, t = 293(2) k, mu = 0.086 mm(-1), the final r = 0.0634 and wr = 0.1752 for 5082 observed reflections with i > 2 sigma(i). the co-crystallization is very stable at room temperature. possibly, a network of n-h center dot center dot center dot o(=c) plays an important role in the structure. meanwhile, the compound emits a weak cyan luminescence with peak maximum band at 458 rim.
WOS关键词	CONFORMATIONAL PROPERTIES ; SELECTIVE EXTRACTION ; RESORCINARENES ; HOST ; CALIXARENES ; PRECONCENTRATION ; MACROCYCLES ; TRANSPORT ; CAVITAND
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Inorganic & Nuclear ; Crystallography
语种	英语
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS记录号	WOS:000274404500019
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2415504
专题	中国科学院大学
通讯作者	Wu Xin-Tao
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Zou Qing-Zhu,Chen Jian-Shan,Fu Rui-Biao,et al. Co-crystallization of resorcin[4]arene tetracarboxylic acid with triethylamine: synthesis and crystal structure[J]. Chinese journal of structural chemistry,2010,29(1):114-120.
APA	Zou Qing-Zhu.,Chen Jian-Shan.,Fu Rui-Biao.,Hu Sheng-Min.,Sheng Tian-Lu.,...&Wu Xin-Tao.(2010).Co-crystallization of resorcin[4]arene tetracarboxylic acid with triethylamine: synthesis and crystal structure.Chinese journal of structural chemistry,29(1),114-120.
MLA	Zou Qing-Zhu,et al."Co-crystallization of resorcin[4]arene tetracarboxylic acid with triethylamine: synthesis and crystal structure".Chinese journal of structural chemistry 29.1(2010):114-120.

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