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	Well-defined skeletal macroporous polymer monoliths fabricated with a novel type of amphiphilic diblock copolymer as a phase separator
	Xin, Peiyong1,2; Qi, Li1; Zhang, Rongyue1,2; Yao, Chunhe1,2; Wei, Xiaoyi1,2; Yang, Gengliang3; Chen, Yi1
刊名	Polymer
	2010-07-08
卷号	51期号:15页码:3410-3415
关键词	Polymer monoliths Amphiphilic diblock copolymer Protein
ISSN号	0032-3861
DOI	10.1016/j.polymer.2010.05.043
通讯作者	Qi, li(qili@iccas.ac.cn)
英文摘要	A novel type of amphiphilic diblock copolymer consisting of butyl methacrylate (bma) block and glycidyl methacrylate (gma) block (bc copolymer) was successfully synthesized via atom transfer radical polymerization (atrp) and then utilized as a phase separator to control the porous structure of poly (butyl methacrylate-co-ethylene dimethacrylate) (poly(bma-co-edma)) monoliths. it has been found that the addition of the bc copolymer had a great impact on the polymerization of the monoliths. when the amount of the bc copolymer added into the synthesizing solution was changed, the porous structure could be varied from aggregated microglobular structure to well-defined three-dimensional (3d) skeletal structure. the porous structure was characterized by scanning electron microscope, mercury intrusion porosimetry and nitrogen adsorption measurement. finally, the separation of proteins demonstrated its potential applications in proteome research. (c) 2010 elsevier ltd. all rights reserved.
WOS关键词	TRANSFER RADICAL POLYMERIZATION ; LIQUID-CHROMATOGRAPHY ; CROSS-LINKING ; MORPHOLOGY ; HPLC
WOS研究方向	Polymer Science
WOS类目	Polymer Science
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000279756000012
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2413493
专题	中国科学院大学
通讯作者	Qi, Li
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Analyt Chem Living Biosyst, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Hebei Univ, Coll Pharm, Baoding 071002, Peoples R China
推荐引用方式 GB/T 7714	Xin, Peiyong,Qi, Li,Zhang, Rongyue,et al. Well-defined skeletal macroporous polymer monoliths fabricated with a novel type of amphiphilic diblock copolymer as a phase separator[J]. Polymer,2010,51(15):3410-3415.
APA	Xin, Peiyong.,Qi, Li.,Zhang, Rongyue.,Yao, Chunhe.,Wei, Xiaoyi.,...&Chen, Yi.(2010).Well-defined skeletal macroporous polymer monoliths fabricated with a novel type of amphiphilic diblock copolymer as a phase separator.Polymer,51(15),3410-3415.
MLA	Xin, Peiyong,et al."Well-defined skeletal macroporous polymer monoliths fabricated with a novel type of amphiphilic diblock copolymer as a phase separator".Polymer 51.15(2010):3410-3415.

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