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Hrtem nanostructural evolution of onion-like spheres in polyacrylonitrile fibres during stabilization and carbonization
Wen, Y.1,2; Li, H.1; Peng, G.1,2; Yang, Y.1; Liu, L.1
刊名Materials science-poland
2010
卷号28期号:2页码:479-490
关键词High resolution transmission electron microscopy Carbon fibre Onion-like sphere
ISSN号0137-1339
通讯作者Yang, y.(yangyg@sxicc.ac.cn)
英文摘要Ultrathin sections of polyacrylonitrile (pan) fibre samples in the stabilization and carbonization stages were studied using high-resolution transmission electron microscopy. supplementary analyses by the fourier transform infrared, x-ray diffraction, thermogravimetry mass spectroscopy and elemental analysishave also been done. results showed that the pan fibres contained nanosized crystallites embedded in a continuous amorphous matrix. amorphous onion-like spherical structures were also observed and their structural evolution was investigated. during the stabilization and carbonization process, the outer layers of the onion-like spheres gradually changed from an orderly layered structure into a disordered, dense structure due to cyclization and cross-linking reaction. during carbonization, the onion-like spheres became more dense and compact due to the merging of the ring structures. after carbonization, the onion-like spheres in the pan fibres eventually turned into dense and amorphous domains of carbon fibres.
WOS关键词CARBON-FIBERS ; OXIDATIVE STABILIZATION ; PRECURSOR FIBERS
WOS研究方向Materials Science
WOS类目Materials Science, Multidisciplinary
语种英语
出版者OFICYNA WYDAWNICZA POLITECHNIKI WROCLAWSKIEJ
WOS记录号WOS:000280734400011
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2412115
专题中国科学院大学
通讯作者Yang, Y.
作者单位1.Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wen, Y.,Li, H.,Peng, G.,et al. Hrtem nanostructural evolution of onion-like spheres in polyacrylonitrile fibres during stabilization and carbonization[J]. Materials science-poland,2010,28(2):479-490.
APA Wen, Y.,Li, H.,Peng, G.,Yang, Y.,&Liu, L..(2010).Hrtem nanostructural evolution of onion-like spheres in polyacrylonitrile fibres during stabilization and carbonization.Materials science-poland,28(2),479-490.
MLA Wen, Y.,et al."Hrtem nanostructural evolution of onion-like spheres in polyacrylonitrile fibres during stabilization and carbonization".Materials science-poland 28.2(2010):479-490.
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