Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes | |
Peng, Lin1,2; Xu, Xiao-Ying1; Wang, Liang-Liang1,2; Huang, Jun1,2; Bai, Jian-Fei1,2; Huang, Qing-Chun1; Wang, Li-Xin1 | |
刊名 | European journal of organic chemistry |
2010-04-01 | |
期号 | 10页码:1849-1853 |
关键词 | Organocatalysis Michael addition Asymmetric synthesis Amines |
ISSN号 | 1434-193X |
DOI | 10.1002/ejoc.200901509 |
通讯作者 | Wang, li-xin(wlxioc@cioc.ac.cn) |
英文摘要 | Highly enantioselective michael addition of acetone to a variety of nitroalkenes promoted by simple chiral primary amine bifunctional catalysts (e.g., noyori's ts-dpen ligand) together with terephthalic acid in excellent yields (84-99%) and enantioselectivities (93-98 % ee) is reported. |
WOS关键词 | ASYMMETRIC CONJUGATE ADDITION ; HYDROGEN-BONDING DONORS ; AMINE-THIOUREA CATALYST ; SYN-ALDOL REACTIONS ; BIFUNCTIONAL ORGANOCATALYSTS ; EFFICIENT ORGANOCATALYSTS ; 1,3-DICARBONYL COMPOUNDS ; PYRROLIDINE SULFONAMIDE ; 1,4-ADDITION REACTIONS ; AROMATIC KETONES |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000276742400003 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2408954 |
专题 | 中国科学院大学 |
通讯作者 | Wang, Li-Xin |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10039, Peoples R China |
推荐引用方式 GB/T 7714 | Peng, Lin,Xu, Xiao-Ying,Wang, Liang-Liang,et al. Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes[J]. European journal of organic chemistry,2010(10):1849-1853. |
APA | Peng, Lin.,Xu, Xiao-Ying.,Wang, Liang-Liang.,Huang, Jun.,Bai, Jian-Fei.,...&Wang, Li-Xin.(2010).Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes.European journal of organic chemistry(10),1849-1853. |
MLA | Peng, Lin,et al."Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes".European journal of organic chemistry .10(2010):1849-1853. |
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