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Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes
Peng, Lin1,2; Xu, Xiao-Ying1; Wang, Liang-Liang1,2; Huang, Jun1,2; Bai, Jian-Fei1,2; Huang, Qing-Chun1; Wang, Li-Xin1
刊名European journal of organic chemistry
2010-04-01
期号10页码:1849-1853
关键词Organocatalysis Michael addition Asymmetric synthesis Amines
ISSN号1434-193X
DOI10.1002/ejoc.200901509
通讯作者Wang, li-xin(wlxioc@cioc.ac.cn)
英文摘要Highly enantioselective michael addition of acetone to a variety of nitroalkenes promoted by simple chiral primary amine bifunctional catalysts (e.g., noyori's ts-dpen ligand) together with terephthalic acid in excellent yields (84-99%) and enantioselectivities (93-98 % ee) is reported.
WOS关键词ASYMMETRIC CONJUGATE ADDITION ; HYDROGEN-BONDING DONORS ; AMINE-THIOUREA CATALYST ; SYN-ALDOL REACTIONS ; BIFUNCTIONAL ORGANOCATALYSTS ; EFFICIENT ORGANOCATALYSTS ; 1,3-DICARBONYL COMPOUNDS ; PYRROLIDINE SULFONAMIDE ; 1,4-ADDITION REACTIONS ; AROMATIC KETONES
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000276742400003
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2408954
专题中国科学院大学
通讯作者Wang, Li-Xin
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 10039, Peoples R China
推荐引用方式
GB/T 7714
Peng, Lin,Xu, Xiao-Ying,Wang, Liang-Liang,et al. Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes[J]. European journal of organic chemistry,2010(10):1849-1853.
APA Peng, Lin.,Xu, Xiao-Ying.,Wang, Liang-Liang.,Huang, Jun.,Bai, Jian-Fei.,...&Wang, Li-Xin.(2010).Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes.European journal of organic chemistry(10),1849-1853.
MLA Peng, Lin,et al."Noyori's ts-dpen ligand: simple yet effective catalyst for the highly enantioselective michael addition of acetone to nitroalkenes".European journal of organic chemistry .10(2010):1849-1853.
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