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Controllable synthesis and magnetism of iron oxides nanorings
Lv, Baoliang1,2; Xu, Yao1; Gao, Qiang1,2; Wu, Dong1; Sun, Yuhan1
刊名Journal of nanoscience and nanotechnology
2010-04-01
卷号10期号:4页码:2348-2359
关键词Iron oxide Nanorings Magnetic property Coercivity
ISSN号1533-4880
DOI10.1166/jnn.2010.2161
通讯作者Xu, yao()
英文摘要Hematite (alpha-fe(2)o(3)) nanorings were prepared via a facile hydrothermal route without using any template. the products were characterized by x-ray powder diffraction (xrd), x-ray photoelectron spectroscopy (xps), scanning electron microscopy (sem), and transmission electron microscopy (tem). on the basis of these characterizations and condition experiments, an "oriented dissolution and recrystallization" mechanism under the effect of h(2)po(4)(-) ions was proposed to explain the formation process of nanoring structure. magnetite (fe(3)o(4)) nanorings were obtained by reducing alpha-fe(2)o(3) nanorings, and then maghemite (gamma-fe(2)o(3)) nanorings were obtained by reoxidizing fe(3)o(4) nanorings. the magnetic properties of these nanorings were investigated, and it was found that these nanorings have higher coercivity and lower saturation magnetization than many other nanostructures of iron oxides. the adsorbed phosphate on the surface and the nanoring morphology might be responsible for this phenomenon. furthermore, it is interesting to find that the coercjvity of the nanorings increased with the increase of d(in)/d(out) (d(in) and d(out) are the inner and outer diameters of the rings, respectively), and a rapid increase was observed at the value of d(in)/d(out) around 0.5.
WOS关键词LARGE-SCALE SYNTHESIS ; MAGHEMITE NANOPARTICLES ; HEMATITE NANOPARTICLES ; LOW-TEMPERATURE ; CRYSTALLINE WALLS ; FLUX-CLOSURE ; ALPHA-FE2O3 ; RINGS ; GAMMA-FE2O3 ; FE3O4
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
语种英语
出版者AMER SCIENTIFIC PUBLISHERS
WOS记录号WOS:000273984900011
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2408604
专题中国科学院大学
通讯作者Xu, Yao
作者单位1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Lv, Baoliang,Xu, Yao,Gao, Qiang,et al. Controllable synthesis and magnetism of iron oxides nanorings[J]. Journal of nanoscience and nanotechnology,2010,10(4):2348-2359.
APA Lv, Baoliang,Xu, Yao,Gao, Qiang,Wu, Dong,&Sun, Yuhan.(2010).Controllable synthesis and magnetism of iron oxides nanorings.Journal of nanoscience and nanotechnology,10(4),2348-2359.
MLA Lv, Baoliang,et al."Controllable synthesis and magnetism of iron oxides nanorings".Journal of nanoscience and nanotechnology 10.4(2010):2348-2359.
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