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Synthesis and properties of alkylbetaine zwitterionic gemini surfactants
Xie, Zhanfeng1,2; Feng, Yujun1
刊名Journal of surfactants and detergents
2010
卷号13期号:1页码:51-57
关键词Gemini surfactant Synthesis Zwitterionic surfactant Critical micelle concentration Rheology Surface tension
ISSN号1097-3958
DOI10.1007/s11743-009-1152-4
通讯作者Feng, yujun(yjfeng@cioc.ac.cn)
英文摘要A series of alkylbetaine zwitterionic gemini surfactants, 1,2-bis[n-methyl-n-carboxymethyl-alkyl-ammonium]ethane (c (n) ab, n = 8, 10, 12, or 14), were synthesized by alkylation of n,n'-dimethylethylenediamine with an alkyl bromide, followed by reaction with sodium 2-bromoacetate. their solution properties were characterized by surface tension, steady-state fluorescence, and rheological measurements. surface-tension measurements showed c (n) ab had lower critical micelle concentration (cmc) and higher efficiency in lowering the surface tension than their corresponding monomeric surfactants. the logcmc of c (n) ab decreased linearly with increasing chain lengths up to 12. viscosity measurements showed only c(10)ab could enhance aqueous solution viscosity at high concentrations.
WOS关键词AQUEOUS-SOLUTION ; HETEROGEMINI SURFACTANTS ; OLIGOMERIC SURFACTANTS ; ACTIVE PROPERTIES ; MICELLIZATION ; FLUORESCENCE ; INTERFACES ; ADSORPTION ; BEHAVIOR
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
语种英语
出版者SPRINGER HEIDELBERG
WOS记录号WOS:000272800600007
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2408600
专题中国科学院大学
通讯作者Feng, Yujun
作者单位1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Xie, Zhanfeng,Feng, Yujun. Synthesis and properties of alkylbetaine zwitterionic gemini surfactants[J]. Journal of surfactants and detergents,2010,13(1):51-57.
APA Xie, Zhanfeng,&Feng, Yujun.(2010).Synthesis and properties of alkylbetaine zwitterionic gemini surfactants.Journal of surfactants and detergents,13(1),51-57.
MLA Xie, Zhanfeng,et al."Synthesis and properties of alkylbetaine zwitterionic gemini surfactants".Journal of surfactants and detergents 13.1(2010):51-57.
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