Synthesis and properties of alkylbetaine zwitterionic gemini surfactants | |
Xie, Zhanfeng1,2; Feng, Yujun1 | |
刊名 | Journal of surfactants and detergents |
2010 | |
卷号 | 13期号:1页码:51-57 |
关键词 | Gemini surfactant Synthesis Zwitterionic surfactant Critical micelle concentration Rheology Surface tension |
ISSN号 | 1097-3958 |
DOI | 10.1007/s11743-009-1152-4 |
通讯作者 | Feng, yujun(yjfeng@cioc.ac.cn) |
英文摘要 | A series of alkylbetaine zwitterionic gemini surfactants, 1,2-bis[n-methyl-n-carboxymethyl-alkyl-ammonium]ethane (c (n) ab, n = 8, 10, 12, or 14), were synthesized by alkylation of n,n'-dimethylethylenediamine with an alkyl bromide, followed by reaction with sodium 2-bromoacetate. their solution properties were characterized by surface tension, steady-state fluorescence, and rheological measurements. surface-tension measurements showed c (n) ab had lower critical micelle concentration (cmc) and higher efficiency in lowering the surface tension than their corresponding monomeric surfactants. the logcmc of c (n) ab decreased linearly with increasing chain lengths up to 12. viscosity measurements showed only c(10)ab could enhance aqueous solution viscosity at high concentrations. |
WOS关键词 | AQUEOUS-SOLUTION ; HETEROGEMINI SURFACTANTS ; OLIGOMERIC SURFACTANTS ; ACTIVE PROPERTIES ; MICELLIZATION ; FLUORESCENCE ; INTERFACES ; ADSORPTION ; BEHAVIOR |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
语种 | 英语 |
出版者 | SPRINGER HEIDELBERG |
WOS记录号 | WOS:000272800600007 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2408600 |
专题 | 中国科学院大学 |
通讯作者 | Feng, Yujun |
作者单位 | 1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Xie, Zhanfeng,Feng, Yujun. Synthesis and properties of alkylbetaine zwitterionic gemini surfactants[J]. Journal of surfactants and detergents,2010,13(1):51-57. |
APA | Xie, Zhanfeng,&Feng, Yujun.(2010).Synthesis and properties of alkylbetaine zwitterionic gemini surfactants.Journal of surfactants and detergents,13(1),51-57. |
MLA | Xie, Zhanfeng,et al."Synthesis and properties of alkylbetaine zwitterionic gemini surfactants".Journal of surfactants and detergents 13.1(2010):51-57. |
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