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	A new tetrathiafulvalene-quinone-tetrathiafulvalene triad: modulation of the intramolecular charge transfer by the electron-transfer process promoted by metal ions
	Zeng, Yan1,2; Zhang, Guanxin1; Zhang, Deqing1; Zhu, Daoben1
刊名	Journal of organic chemistry
	2009-06-05
卷号	74期号:11页码:4375-4378
ISSN号	0022-3263
DOI	10.1021/jo9007332
通讯作者	Zhang, guanxin()
英文摘要	Electron transfer can occur from the ttf units to the substituted quinone unit in a new ttf-quinone-ttf triad 1 containing the n,n-dialkylaniline-substituted quinone unit flanked by two ttf units, in the presence of metal ions (pb(2+), zn(2+), and sc(3+)). simultaneously, the corresponding charge transfer within the substituted quinone unit becomes weak in the presence of metal ions. moreover, the metal ion-promoted electron transfer and the intramolecular charge transfer can be tuned by alternating uv and visible light irradiation in the presence of spiropyran.
WOS关键词	NADH MODEL-COMPOUND ; SUBSTITUTED TETRATHIAFULVALENE ; PHOTOCHROMIC SPIROPYRAN ; FLUORESCENCE-SWITCH ; COLORIMETRIC CHEMOSENSOR ; QUANTITATIVE-EVALUATION ; MOLECULAR SWITCHES ; HYDRIDE-TRANSFER ; AQUEOUS-SOLUTION ; FERRIC ION
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000266545200053
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2396059
专题	中国科学院大学
通讯作者	Zhang, Guanxin
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Organ Solids Lab, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zeng, Yan,Zhang, Guanxin,Zhang, Deqing,et al. A new tetrathiafulvalene-quinone-tetrathiafulvalene triad: modulation of the intramolecular charge transfer by the electron-transfer process promoted by metal ions[J]. Journal of organic chemistry,2009,74(11):4375-4378.
APA	Zeng, Yan,Zhang, Guanxin,Zhang, Deqing,&Zhu, Daoben.(2009).A new tetrathiafulvalene-quinone-tetrathiafulvalene triad: modulation of the intramolecular charge transfer by the electron-transfer process promoted by metal ions.Journal of organic chemistry,74(11),4375-4378.
MLA	Zeng, Yan,et al."A new tetrathiafulvalene-quinone-tetrathiafulvalene triad: modulation of the intramolecular charge transfer by the electron-transfer process promoted by metal ions".Journal of organic chemistry 74.11(2009):4375-4378.

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