Photoinduced triplet-triplet energy transfer via the 2-ureido-4[1h]-pyrimidinone self-complementary quadruple hydrogen-bonded module | |
Wang, Su-Min; Yu, Mao-Lin; Ding, Jie; Tung, Chen-Ho; Wu, Li-Zhu1 | |
刊名 | Journal of physical chemistry a |
2008-05-01 | |
卷号 | 112期号:17页码:3865-3869 |
ISSN号 | 1089-5639 |
DOI | 10.1021/jp711807s |
通讯作者 | Wu, li-zhu(lzwu@mail.ipc.ac.cn) |
英文摘要 | Phosphorescence quenching and flash photolysis experiments; demonstrate that photoinduced intra-assembly triplet-triplet energy transfer can take place via a 2-ureido-4[1h]-pyrimidinone-bridged benzophenone-naphthalene assembly i with a rate constant of 3.0 x 10(6) s(-1) and an efficiency of 95% in ch2cl2. this new finding suggests that with high binding strength and directionality, the 2-ureido-4[1h]-pyrimidinone hydrogen-bonded module may serve as a new model to illustrate the fundamental principles governing the triplet-triplet energy-transfer process through hydrogen bonds. |
WOS关键词 | PHOTOISOMERIZATION INVOLVING KETONE ; WEAKLY INTERACTING CHROMOPHORES ; ELECTRON-TRANSFER ; SINGLET-SINGLET ; SYSTEMS ; NORBORNADIENE ; DEPENDENCE ; ACCEPTOR ; BRIDGE ; DONOR |
WOS研究方向 | Chemistry ; Physics |
WOS类目 | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000255292200009 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2393568 |
专题 | 中国科学院大学 |
通讯作者 | Wu, Li-Zhu |
作者单位 | 1.Chinese Acad Sci, Lab Organ Optoelect Funct Mat & Mol Engn, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Su-Min,Yu, Mao-Lin,Ding, Jie,et al. Photoinduced triplet-triplet energy transfer via the 2-ureido-4[1h]-pyrimidinone self-complementary quadruple hydrogen-bonded module[J]. Journal of physical chemistry a,2008,112(17):3865-3869. |
APA | Wang, Su-Min,Yu, Mao-Lin,Ding, Jie,Tung, Chen-Ho,&Wu, Li-Zhu.(2008).Photoinduced triplet-triplet energy transfer via the 2-ureido-4[1h]-pyrimidinone self-complementary quadruple hydrogen-bonded module.Journal of physical chemistry a,112(17),3865-3869. |
MLA | Wang, Su-Min,et al."Photoinduced triplet-triplet energy transfer via the 2-ureido-4[1h]-pyrimidinone self-complementary quadruple hydrogen-bonded module".Journal of physical chemistry a 112.17(2008):3865-3869. |
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