A nor fluorescent logic gate based on n-(9-anthracylmethyl)-l-histidine | |
Zong Guo-Qiang1,2; Lue Gong-Xuan1 | |
刊名 | Acta physico-chimica sinica |
2008-10-01 | |
卷号 | 24期号:10页码:1902-1906 |
关键词 | Fluorescent logic gate L-histidine Anthracene Cu2+ Ni2+ |
ISSN号 | 1000-6818 |
DOI | 10.3866/pku.whxb20081028 |
通讯作者 | Lue gong-xuan(gxlu@lzb.ac.cn) |
英文摘要 | A new compound, n-(9-anthracylmethyl)-l-histidine (1). was synthesized and characterized by elemental analysis, electrospray ionization mass spectrometry (esi-ms), h-1-nmr. and c-13-nmr, etc. the effects of ph values and metal ions on the fluorescent intensity of compound 1 were studied. in neutral aqueous solutions, the fluorescence intensity of compound 1 increased upon addition of zn2+ or cd2+, while other metal ions (pb2+, co2+, hg2+, ni2+, and cu2+) quenched the fluorescence. among these metal ions, cu2+ and ni2+ had the strongest quenching capacity. they both formed a stable complex with compound 1 (1:2 molar ratio), and the complex constants were 2.88x10(6) and 1.12x10(6) l-2.mol(-2), respectively. the experimental results showed that static quenching was involved in adding cu2+ or ni2+ in aqueous solution of compound 1. on the basis of these studies. it nor fluorescent molecular logic gate was fabricated with cu2+ and ni2+ as two inputs and with emission of anthracene as the output. |
WOS关键词 | SWITCH ; PYRENE ; SENSOR ; INPUTS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | PEKING UNIV PRESS |
WOS记录号 | WOS:000260347300028 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2391060 |
专题 | 中国科学院大学 |
通讯作者 | Lue Gong-Xuan |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zong Guo-Qiang,Lue Gong-Xuan. A nor fluorescent logic gate based on n-(9-anthracylmethyl)-l-histidine[J]. Acta physico-chimica sinica,2008,24(10):1902-1906. |
APA | Zong Guo-Qiang,&Lue Gong-Xuan.(2008).A nor fluorescent logic gate based on n-(9-anthracylmethyl)-l-histidine.Acta physico-chimica sinica,24(10),1902-1906. |
MLA | Zong Guo-Qiang,et al."A nor fluorescent logic gate based on n-(9-anthracylmethyl)-l-histidine".Acta physico-chimica sinica 24.10(2008):1902-1906. |
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