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Chiral transformation of cyanine dye aggregates induced by small peptides
Yang, Qianfan1,2; Xiang, Junfeng1; Li, Qian1,2; Yan, Wenpeng3; Zhou, Qiuju1,2; Tang, Yalin1; Xu, Guangzhi1
刊名Journal of physical chemistry b
2008-07-24
卷号112期号:29页码:8783-8787
ISSN号1520-6106
DOI10.1021/jp803076d
通讯作者Tang, yalin(tangyl@iccas.ac.cn)
英文摘要Three small peptides (k4, k5, and k6) with different length were designed to induce the transformation of the assembled state and the chirality of cyanine dye supramolecule. the absorption and circular dichroism (cd) results indicated that, the peptides tend to induce cyanine dye to h-aggregation, competed with na+ in pbs, which would induce dye to j-aggregation. meanwhile, all three peptides could influence the chirality of both j-aggregates induced by na+ and h-aggregates, among which k6 could induce chiral reversion of j-aggregates. furthermore, molecular modeling and energy calculation results have shown that the peptides with different chain length have different conformations. this might be the reason for cyanine dye to form the different chiral assembly induced by these oligo-peptide templates.
WOS关键词HUMAN SERUM-ALBUMIN ; CIRCULAR-DICHROISM ; PORPHYRINS ; STATE ; PROBE
WOS研究方向Chemistry
WOS类目Chemistry, Physical
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000257724000050
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2388858
专题中国科学院大学
通讯作者Tang, Yalin
作者单位1.Chinese Acad Sci, ICCAS, Beijing Natl Lab Mol Sci,Inst Chem,Ctr Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Yang, Qianfan,Xiang, Junfeng,Li, Qian,et al. Chiral transformation of cyanine dye aggregates induced by small peptides[J]. Journal of physical chemistry b,2008,112(29):8783-8787.
APA Yang, Qianfan.,Xiang, Junfeng.,Li, Qian.,Yan, Wenpeng.,Zhou, Qiuju.,...&Xu, Guangzhi.(2008).Chiral transformation of cyanine dye aggregates induced by small peptides.Journal of physical chemistry b,112(29),8783-8787.
MLA Yang, Qianfan,et al."Chiral transformation of cyanine dye aggregates induced by small peptides".Journal of physical chemistry b 112.29(2008):8783-8787.
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