Chiral transformation of cyanine dye aggregates induced by small peptides | |
Yang, Qianfan1,2; Xiang, Junfeng1; Li, Qian1,2; Yan, Wenpeng3; Zhou, Qiuju1,2; Tang, Yalin1; Xu, Guangzhi1 | |
刊名 | Journal of physical chemistry b |
2008-07-24 | |
卷号 | 112期号:29页码:8783-8787 |
ISSN号 | 1520-6106 |
DOI | 10.1021/jp803076d |
通讯作者 | Tang, yalin(tangyl@iccas.ac.cn) |
英文摘要 | Three small peptides (k4, k5, and k6) with different length were designed to induce the transformation of the assembled state and the chirality of cyanine dye supramolecule. the absorption and circular dichroism (cd) results indicated that, the peptides tend to induce cyanine dye to h-aggregation, competed with na+ in pbs, which would induce dye to j-aggregation. meanwhile, all three peptides could influence the chirality of both j-aggregates induced by na+ and h-aggregates, among which k6 could induce chiral reversion of j-aggregates. furthermore, molecular modeling and energy calculation results have shown that the peptides with different chain length have different conformations. this might be the reason for cyanine dye to form the different chiral assembly induced by these oligo-peptide templates. |
WOS关键词 | HUMAN SERUM-ALBUMIN ; CIRCULAR-DICHROISM ; PORPHYRINS ; STATE ; PROBE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Physical |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000257724000050 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2388858 |
专题 | 中国科学院大学 |
通讯作者 | Tang, Yalin |
作者单位 | 1.Chinese Acad Sci, ICCAS, Beijing Natl Lab Mol Sci,Inst Chem,Ctr Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Qianfan,Xiang, Junfeng,Li, Qian,et al. Chiral transformation of cyanine dye aggregates induced by small peptides[J]. Journal of physical chemistry b,2008,112(29):8783-8787. |
APA | Yang, Qianfan.,Xiang, Junfeng.,Li, Qian.,Yan, Wenpeng.,Zhou, Qiuju.,...&Xu, Guangzhi.(2008).Chiral transformation of cyanine dye aggregates induced by small peptides.Journal of physical chemistry b,112(29),8783-8787. |
MLA | Yang, Qianfan,et al."Chiral transformation of cyanine dye aggregates induced by small peptides".Journal of physical chemistry b 112.29(2008):8783-8787. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论