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Morphology transition and aggregation-induced emission of an intramolecular charge-transfer compound
Xu, Jialiang1,3; Liu, Xiaofeng1,3; Lv, Jing1,3; Zhu, Mei1,3; Huang, Changshui1,3; Zhou, Weidong1,3; Yin, Xiaodong1,3; Liu, Huibiao1; Li, Yuliang1; Ye, Hanping2
刊名Langmuir
2008-04-15
卷号24期号:8页码:4231-4237
ISSN号0743-7463
DOI10.1021/la703662w
通讯作者Li, yuliang(ylli@iccas.ac.cn)
英文摘要An intramolecular charge-transfer (ict) compound, (tcbd)(2)opv(3), has been synthesized and fabricated into one-dimensional nanotubes by a reprecipitation method. the observation of sem and tem showed the nanotubes were formed from their zero-dimensional precursors of hollow nanospheres. reconstruction was found to happen during the morphology transition progress. the morphology transition and reconstruction are proposed to be a "curvature strain releasing" process driven by donor-acceptor dipole-dipole interactions. an aggregation-induced emission (aie) effect was observed for (tcbd)(2)opv(3). both aggregates of vesicles and nanotubes were observed to be good red emitters with near-infrared end emission of 750-850 nm, which endows the material with potential applications in the fields of optical devices, biosensors, and biolabels.
WOS关键词ORGANIC NANOPARTICLES ; ENHANCED EMISSION ; ENERGY-TRANSFER ; PI-ORGANOGELS ; VESICLES ; MOLECULES ; NANOTUBES ; NANOWIRES ; TEMPLATE ; NANOMATERIALS
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Materials Science, Multidisciplinary
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000254647400078
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2388472
专题中国科学院大学
通讯作者Li, Yuliang
作者单位1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, CAS Key Lab Organ Solids,BNLMS, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Xu, Jialiang,Liu, Xiaofeng,Lv, Jing,et al. Morphology transition and aggregation-induced emission of an intramolecular charge-transfer compound[J]. Langmuir,2008,24(8):4231-4237.
APA Xu, Jialiang.,Liu, Xiaofeng.,Lv, Jing.,Zhu, Mei.,Huang, Changshui.,...&Ye, Hanping.(2008).Morphology transition and aggregation-induced emission of an intramolecular charge-transfer compound.Langmuir,24(8),4231-4237.
MLA Xu, Jialiang,et al."Morphology transition and aggregation-induced emission of an intramolecular charge-transfer compound".Langmuir 24.8(2008):4231-4237.
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