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	Photocatalytic h-2 evolution from water based on cyclometalated platinum(ii) complex
	Xu, Quanqing1,2; Fu, Wen-fu1,2,3; Zhang, Guiju1,2; Bian, Zhaoyong1,2; Zhang, Junfeng3; Han, Xu3; Xu, Wenzhan3
刊名	Catalysis communications
	2008-10-10
卷号	10期号:1页码:49-52
关键词	Platinum(ii) complex Cyclometalated ligand Photocatalysis Hydrogen
ISSN号	1566-7367
DOI	10.1016/j.catcom.2008.07.034
通讯作者	Fu, wen-fu(wf_fu@yahoo.com.cn)
英文摘要	Cyclometalated platinum(ii) complex, [clpt((cnnphme)-n-lambda-n-lambda)] (1) ((hcnnphme)-n-lambda-n-lambda = 4-(p-tolyl)-6-phenyl-2,2'-bipyridine) was found to be an efficient photosensitizer for photocatalytic hydrogen evolution from water, 98 turnovers of hydrogen were obtained after 10 h irradiation of solution containing mv2+ (4,4'-dimethyl-2,2'-bipyridinium), triethanolamine (teoa), photosensitizer and colloidal pt, which is far effective than that of platinum(ii) terpyridyl complex [clpt((nnnphme)-n-lambda-n-lambda)]clo4 (2) ((nnnphme)-n-lambda-n-lambda = 4'-(p-tolyl)-2,2':6'.2 ''-terpyridine). net photocatalytic reduction of mv2+ by the complexes in the presence of teoa in ch3cn/h2o solvents were observed and compared upon irradiation (lambda > 400 nm). (c) 2008 elsevier b.v. all rights reserved.
WOS关键词	VISIBLE-LIGHT IRRADIATION ; EXCITED-STATE PROPERTIES ; HYDROGEN-PRODUCTION ; AQUEOUS-SOLUTIONS ; COLLOIDAL PLATINUM ; ELECTRON-TRANSFER ; MOLECULAR DEVICE ; GENERATION ; 6-PHENYL-2,2'-BIPYRIDINES ; REDUCTION
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000260452200010
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2387644
专题	中国科学院大学
通讯作者	Fu, Wen-fu
作者单位	1.Chinese Acad Sci, Lab Organ Optoelect Funct Mat & Mol Engn, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Yunnan Normal Univ, Coll Chem & Chem Engn, Kunming 650092, Peoples R China
推荐引用方式 GB/T 7714	Xu, Quanqing,Fu, Wen-fu,Zhang, Guiju,et al. Photocatalytic h-2 evolution from water based on cyclometalated platinum(ii) complex[J]. Catalysis communications,2008,10(1):49-52.
APA	Xu, Quanqing.,Fu, Wen-fu.,Zhang, Guiju.,Bian, Zhaoyong.,Zhang, Junfeng.,...&Xu, Wenzhan.(2008).Photocatalytic h-2 evolution from water based on cyclometalated platinum(ii) complex.Catalysis communications,10(1),49-52.
MLA	Xu, Quanqing,et al."Photocatalytic h-2 evolution from water based on cyclometalated platinum(ii) complex".Catalysis communications 10.1(2008):49-52.

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