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	Trinuclear metal cluster complexes containing fischer-type carbene group from oxidative addition reactions of tris(n,n-diethyldithiocarbamato)cobalt with co-2(co)(8) and ru-3(co)(12)
	Yang, Jing-Mu1,2; Hu, Bin1; Xia, Chun-Gu1
刊名	Journal of cluster science
	2008-12-01
卷号	19期号:4页码:615-621
关键词	Trinuclear metal cluster Fischer-type carbene Thiocarboxamido ligand Crystal structure
ISSN号	1040-7278
DOI	10.1007/s10876-008-0201-x
通讯作者	Xia, chun-gu(cgxia@lzb.ac.cn)
英文摘要	Two new fischer-type carbene-containing trinuclear transition-metal clusters: (mu (3)-s)co-3(co)(7)[mu, eta (2)-scnet2] 1 and coru2(co)(9)[mu (3), eta (2)-scnet2] 2 were obtained by the reaction of tris(n,n-diethyldithiocarbamato)cobalt with co-2(co)(8) and ru-3(co)(12). these clusters contain thiocarboxamido ligand in different coordination modes. the thiocarboxamido ligand served as monometalated or dimetalated sulfur(diethy1amino) carbene ligand in these clusters. clusters 1 and 2 were characterized by ir, h-1 nmr, and single-crystal x-ray diffraction.
WOS关键词	MOLECULAR-STRUCTURE ; BOND-CLEAVAGE ; LIGANDS ; CRYSTAL ; SINGLE
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	SPRINGER/PLENUM PUBLISHERS
WOS记录号	WOS:000261751100006
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2386382
专题	中国科学院大学
通讯作者	Xia, Chun-Gu
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Yang, Jing-Mu,Hu, Bin,Xia, Chun-Gu. Trinuclear metal cluster complexes containing fischer-type carbene group from oxidative addition reactions of tris(n,n-diethyldithiocarbamato)cobalt with co-2(co)(8) and ru-3(co)(12)[J]. Journal of cluster science,2008,19(4):615-621.
APA	Yang, Jing-Mu,Hu, Bin,&Xia, Chun-Gu.(2008).Trinuclear metal cluster complexes containing fischer-type carbene group from oxidative addition reactions of tris(n,n-diethyldithiocarbamato)cobalt with co-2(co)(8) and ru-3(co)(12).Journal of cluster science,19(4),615-621.
MLA	Yang, Jing-Mu,et al."Trinuclear metal cluster complexes containing fischer-type carbene group from oxidative addition reactions of tris(n,n-diethyldithiocarbamato)cobalt with co-2(co)(8) and ru-3(co)(12)".Journal of cluster science 19.4(2008):615-621.

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