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	Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}]
	Yang, Jing-Mu1,2; Hu, Bin1; Ge, Jin1,2; Xia, Chun-Gu1
刊名	Journal of chemical research-s
	2008-06-01
期号	6页码:322-323
关键词	Homometallic chiral cluster Enantioseparation Acetylferrocenyl-thiosemicarbazone X-ray structure
ISSN号	0308-2342
DOI	10.3184/030823408x327884
通讯作者	Xia, chun-gu(cgxia@lzb.ac.cn)
英文摘要	Reaction of ru-3(co)(12) with the thio-schiff base ligand acetylferrocenyl-thiosemicarbazone provides a one-step synthesis of the chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}] as a racemic mixture. one molecule of thiosemicarbazone was consumed in the cluster formation process, in which the ligand was deprotonated and acted as a bidentate n, s donor as well as bridging. the title cluster has been characterised by nmr, ir, hplc and an x-ray structure determination.
WOS关键词	COORDINATION
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	SCIENCE REVIEWS LTD
WOS记录号	WOS:000259553600007
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2385057
专题	中国科学院大学
通讯作者	Xia, Chun-Gu
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Yang, Jing-Mu,Hu, Bin,Ge, Jin,et al. Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}][J]. Journal of chemical research-s,2008(6):322-323.
APA	Yang, Jing-Mu,Hu, Bin,Ge, Jin,&Xia, Chun-Gu.(2008).Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}].Journal of chemical research-s(6),322-323.
MLA	Yang, Jing-Mu,et al."Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [ru-3(co)(9){1,2-mu-fcc(ch3) = nnc(s)nhch3}]".Journal of chemical research-s .6(2008):322-323.

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