Solution-processable erbium - ytterbium complex for potential planar optical amplifier application | |
Song, Limei; Liu, Xinhou; Zhen, Zhen; Chen, Cong; Zhang, Daming | |
刊名 | Journal of materials chemistry |
2007 | |
卷号 | 17期号:43页码:4586-4590 |
ISSN号 | 0959-9428 |
DOI | 10.1039/b709237g |
通讯作者 | Song, limei() |
英文摘要 | Novel erbium and erbium-ytterbium complexes based on 4-pentylbenzoate (pba) groups and 1,10-phenanthroline (phen) ligands have been synthesized and structurally characterized. the x-ray single crystal structure of the erbium-ytterbium complex indicates that it is a binuclear complex model with a short metal-to-metal distance (4.269 a), which facilitates the intramolecular yb-er energy-transfer process in the erbium-ytterbium complex. the optical properties for solid state films of the erbium-ytterbium complex prepared by spin-coating technique were studied in detail. the nir pl spectrum of the film shows considerable room temperature emission at 1.53 mm with a large bandwidth (full width at half maximum) of 72 nm. the planar waveguide of the complex is capable of guiding 1550 nm light with low loss. the mechanism for the formation of high-quality films is also proposed according to the structural investigation. our results show that the erbium-ytterbium complex film has promising potential for the planar optical amplifier application. |
WOS关键词 | WAVE-GUIDE AMPLIFIERS ; NEAR-INFRARED LUMINESCENCE ; PHOTOLUMINESCENCE ; FILMS ; GAIN ; ER3+ |
WOS研究方向 | Chemistry ; Materials Science |
WOS类目 | Chemistry, Physical ; Materials Science, Multidisciplinary |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000250554500014 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2381592 |
专题 | 中国科学院大学 |
通讯作者 | Song, Limei |
作者单位 | 1.Chinese Acad Sci, Inst Tech Phys & Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China |
推荐引用方式 GB/T 7714 | Song, Limei,Liu, Xinhou,Zhen, Zhen,et al. Solution-processable erbium - ytterbium complex for potential planar optical amplifier application[J]. Journal of materials chemistry,2007,17(43):4586-4590. |
APA | Song, Limei,Liu, Xinhou,Zhen, Zhen,Chen, Cong,&Zhang, Daming.(2007).Solution-processable erbium - ytterbium complex for potential planar optical amplifier application.Journal of materials chemistry,17(43),4586-4590. |
MLA | Song, Limei,et al."Solution-processable erbium - ytterbium complex for potential planar optical amplifier application".Journal of materials chemistry 17.43(2007):4586-4590. |
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