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	A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex
	Wu, Ming-Yan; Yuan, Da-Qiang; Chen, Bai-Quan; Huang, You-Gui; Jiang, Feilong; Hong, Mao-Chun
刊名	Supramolecular chemistry
	2007
卷号	19期号:6页码:411-417
关键词	P-sulfonatothiacalix[4] arene Copper Supramolecular capsule Crystal structure
ISSN号	1061-0278
DOI	10.1080/10610270601064736
通讯作者	Hong, mao-chun(hmc@fjirsm.ac.cn)
英文摘要	The reaction of tetrasodium p-sulfonatothiacalix[4] arene ( na(4)h(4)tcas), copper( ii) nitrate and pyridine n- oxide ( pno) afforded a yellow copper( ii)-p-sulfonatothiacalix[ 4] arene complex. x-ray diffraction analysis displays that it is an interesting dimeric supramolecular capsule, [cu-2( pno)(2)( h2o)(6)](4+), [( h(6)tcas)(2)](4+)center dot 22h(2)o, in which two pno molecules bridge the two cu ii ions in the o,o'- mu(2) mode and the hydrophobic aromatic rings point into the cavities of the thiacalixarenes. interestingly, the thiacalixarenes pack themselves into the closed pores through pi center dot center dot center dot pi interactions in ab plane, and these pores further link to each other through hydrogen bonding to construct infinite hydrophilic tunnels, which fill with the disordered water molecules as the guests.
WOS关键词	MOLECULAR CAPSULES ; METAL-COMPLEXES ; COORDINATION ; ENCAPSULATION ; CONFINEMENT ; SUPERANIONS ; CALIXARENE ; BILAYERS ; CATIONS ; SITES
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	TAYLOR & FRANCIS LTD
WOS记录号	WOS:000250011400008
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2380507
专题	中国科学院大学
通讯作者	Hong, Mao-Chun
作者单位	Chinese Acad Sci, Fujian Inst Res Struct Matter, Grad Sch, State Key Lab Struct Chem, Fujian 350002, Fuzhou, Peoples R China
推荐引用方式 GB/T 7714	Wu, Ming-Yan,Yuan, Da-Qiang,Chen, Bai-Quan,et al. A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex[J]. Supramolecular chemistry,2007,19(6):411-417.
APA	Wu, Ming-Yan,Yuan, Da-Qiang,Chen, Bai-Quan,Huang, You-Gui,Jiang, Feilong,&Hong, Mao-Chun.(2007).A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex.Supramolecular chemistry,19(6),411-417.
MLA	Wu, Ming-Yan,et al."A p-sulfonatothiacalix[4] arene supramolecular capsule containing a dinuclear copper(ii) complex".Supramolecular chemistry 19.6(2007):411-417.

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