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	Synthesis and nonlinear optical properties of fulleropyrrolidine derivatives
	Huo Yan-Ping; Zeng He-Ping; Jiang Huan-Feng; Liu Jun-Hui; Mao Yan-Li
刊名	Chinese journal of organic chemistry
	2006-12-01
卷号	26期号:12页码:1657-1662
关键词	Fulleropyrrolidine Z-scan Third-order nonlinear optical hyperpolarizability
ISSN号	0253-2786
通讯作者	Zeng he-ping(zenghp@scnu.edu.cn)
英文摘要	A series of azomethine ylides were prepared through the reaction between the different substituted conjugated aldehydes and sarcosine. further 1,3-dipolar cycloaddition of these azomethine ylides to c-60 gave a series of new fulleropyrrolidine derivatives 1 similar to 9. the molecular structures were identified and characterized by h-1 nmr, c-13 nmr, ftir, uv-vis and fab-ms spectra. the third-order nonlinear optical hyperpolarizabilities gamma((3)) were obtained under picosecond laser by z-scan technique. it was found that the gamma((3)) value of 3 (4.14 x 10(-33) esu) is the largest which indicates that the gamma((3)) values become larger with the increasing length of nt. we also found that different substituents at the alpha position of the thiophene rings (2, 5, 1 and 4), different position of n atom of quinoline (7 and 8) and different kinds of conjugate chain have different effects on the nonlinear optical properties of fulleropyrrolidine dyads.
WOS关键词	PHOTOINDUCED ELECTRON-TRANSFER ; DIELS-ALDER REACTION ; CHARGE-TRANSFER ; PHOTOPHYSICAL PROPERTIES ; C-60 ; FULLERENES ; SPECTROSCOPY ; MOLECULES ; SPECTRA ; DESIGN
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	SCIENCE CHINA PRESS
WOS记录号	WOS:000242750700006
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2379474
专题	中国科学院大学
通讯作者	Zeng He-Ping
作者单位	1.S China Univ Technol, Inst Funct Mol, Guangzhou 510641, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Henan Univ, Inst Phys & Informat Phtoelectron, Kaifeng 475001, Peoples R China
推荐引用方式 GB/T 7714	Huo Yan-Ping,Zeng He-Ping,Jiang Huan-Feng,et al. Synthesis and nonlinear optical properties of fulleropyrrolidine derivatives[J]. Chinese journal of organic chemistry,2006,26(12):1657-1662.
APA	Huo Yan-Ping,Zeng He-Ping,Jiang Huan-Feng,Liu Jun-Hui,&Mao Yan-Li.(2006).Synthesis and nonlinear optical properties of fulleropyrrolidine derivatives.Chinese journal of organic chemistry,26(12),1657-1662.
MLA	Huo Yan-Ping,et al."Synthesis and nonlinear optical properties of fulleropyrrolidine derivatives".Chinese journal of organic chemistry 26.12(2006):1657-1662.

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