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	A novel chiral framework constructed through three-fold interpenetration of (4,4) nets of ni(ii)-muconate-4,4 '-bipyridine
	Chen, BQ; Jiang, FL; Han, L; Wu, BL; Yuan, DQ; Wu, MY; Hong, MC
刊名	Inorganic chemistry communications
	2006-04-01
卷号	9期号:4页码:371-374
关键词	Interpenetration framework Magnetism Muconate Chirality
ISSN号	1387-7003
DOI	10.1016/j.inoche.2006.01.002
通讯作者	Hong, mc(hmc@ms.fjirsm.ac.cn)
英文摘要	The assembly of ni(ii) ions with linear spacers trans,trans-muconic acid (h,l) and 4,4'-bipyridine (4,4'-bpy) has afforded a compound, [ni(l)(4,4'-bpy)(h2o)(2)](n) (1). single crystal x-ray diffraction analysis reveals that both 4,4'-bpy and deprotonated h2l act as linear bridges to bind square-planar ni(ii) nodes. achiral ligands 4,4'-bpy induced in a chiral configuration link metal nodes into chiral chains, which are further bound into homochiral sheets by rigid l. finally, a novel 3d chiral framework forms through three-fold slantwise interpenetration of those chiral (4,4) nets. the magnetic studies in the range 2-300 k show that magnetic behavior of i possesses a large zero-field splitting of ni(ii) ions and an anti-ferromagnetic interaction between metal centers. (c) 2006 published by elsevier b.v.
WOS关键词	COORDINATION POLYMERS ; SPONTANEOUS RESOLUTION ; HOMOCHIRAL HELIX ; TRANSITION-METAL ; RATIONAL DESIGN ; COMPLEXES ; POLYHEDRA ; NETWORKS ; SYMMETRY
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000236430700007
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2379102
专题	中国科学院大学
通讯作者	Hong, MC
作者单位	Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Grad Sch, Fuzhou 350002, Fujian, Peoples R China
推荐引用方式 GB/T 7714	Chen, BQ,Jiang, FL,Han, L,et al. A novel chiral framework constructed through three-fold interpenetration of (4,4) nets of ni(ii)-muconate-4,4 '-bipyridine[J]. Inorganic chemistry communications,2006,9(4):371-374.
APA	Chen, BQ.,Jiang, FL.,Han, L.,Wu, BL.,Yuan, DQ.,...&Hong, MC.(2006).A novel chiral framework constructed through three-fold interpenetration of (4,4) nets of ni(ii)-muconate-4,4 '-bipyridine.Inorganic chemistry communications,9(4),371-374.
MLA	Chen, BQ,et al."A novel chiral framework constructed through three-fold interpenetration of (4,4) nets of ni(ii)-muconate-4,4 '-bipyridine".Inorganic chemistry communications 9.4(2006):371-374.

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