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Effects of the polybutadiene/poly(styrene-co-acrylonitrile) ratio in a polybutadiene-g-poly(styrene-co-acrylonitrile) impact modifier on the morphology and mechanical behavior of acrylonitrile-butadiene-styrene blends
Xu, XF; Yang, HD; Zhang, HX
刊名Journal of applied polymer science
2005-12-05
卷号98期号:5页码:2165-2171
关键词Mechanical properties Morphology Polybutadiene
ISSN号0021-8995
DOI10.1002/app.22389
通讯作者Xu, xf(zhhx@ciac.jl.cn)
英文摘要Polybutadiene-g-poly(styrene-co-acrylonitrile) (pb-g-san) impact modifiers with different polybutadiene (pb)/poly(styrene-co-acrylonitrile) (san) ratios ranging from 20.5/79.5 to 82.7/17.3 were synthesized by seeded emulsion polymerization. acrylonitrile-butadiene-styrene (abs) blends with a constant rubber concentration of 15 wt % were prepared by the blending of these pb-g-san copolymers and san resin. the influence of the pb/san ratio in the pb-g-san impact modifier on the mechanical behavior and phase morphology of abs blends was investigated. the mechanical tests showed that the impact strength and yield strength of the abs blends had their maximum values as the pb/san ratio in the pb-g-san copolymer increased. a dynamic mechanical analysis of the abs blends showed that the glass-transition temperature of the rubbery phase shifted to a lower temperature, the maximum loss peak height of the rubbery phase increased and then decreased, and the storage modulus of the abs blends increased with an increase in the pb/san ratio in the pb-g-san impact modifier. the morphological results of the abs blends showed that the dispersion of rubber particle in the matrix and its internal structure were influenced by the pb/san ratio in the pb-g-san impact modifiers. (c) 2005 wiley periodicals, inc.
WOS关键词ELASTOMER-MODIFIED EPOXIES ; PARTICLE-VOLUME FRACTION ; TOUGHENING MECHANISMS ; ABS MATERIALS ; DEFORMATION ; POLYMERS ; SIZE ; TEMPERATURE ; FRACTURE ; PLASTICS
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
出版者JOHN WILEY & SONS INC
WOS记录号WOS:000232572600042
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2377359
专题中国科学院大学
通讯作者Xu, XF
作者单位1.Chinese Acad Sci, Grad Sch, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
2.Changchun Univ Technol, Inst Chem Engn, Changchun 130012, Peoples R China
推荐引用方式
GB/T 7714
Xu, XF,Yang, HD,Zhang, HX. Effects of the polybutadiene/poly(styrene-co-acrylonitrile) ratio in a polybutadiene-g-poly(styrene-co-acrylonitrile) impact modifier on the morphology and mechanical behavior of acrylonitrile-butadiene-styrene blends[J]. Journal of applied polymer science,2005,98(5):2165-2171.
APA Xu, XF,Yang, HD,&Zhang, HX.(2005).Effects of the polybutadiene/poly(styrene-co-acrylonitrile) ratio in a polybutadiene-g-poly(styrene-co-acrylonitrile) impact modifier on the morphology and mechanical behavior of acrylonitrile-butadiene-styrene blends.Journal of applied polymer science,98(5),2165-2171.
MLA Xu, XF,et al."Effects of the polybutadiene/poly(styrene-co-acrylonitrile) ratio in a polybutadiene-g-poly(styrene-co-acrylonitrile) impact modifier on the morphology and mechanical behavior of acrylonitrile-butadiene-styrene blends".Journal of applied polymer science 98.5(2005):2165-2171.
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