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	An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties
	Liu, HT; He, P; Li, ZY; Sun, CY; Shi, LH; Liu, Y; Zhu, GY; Li, JH
刊名	Electrochemistry communications
	2005-12-01
卷号	7期号:12页码:1357-1363
关键词	Carbon paste electrode Ionic liquid Bulk-modified Polyoxomolybdate Electrocatalytic activity
ISSN号	1388-2481
DOI	10.1016/j.elecom.2005.09.018
通讯作者	Li, jh(jhli@mail.tsinghua.edu.cn)
英文摘要	The replacement of a non-conductive organic binder with a conductive room temperature ionic liquid in fabricating carbon paste electrode has been made. this new electrode due to its enhanced conductivity presented very large current response from electroactive substrates. the novel carbon paste electrode was bulk-modified via the uniform dispersion of keggin-type phospho polyoxomolybdate pmo12o403- (pmo12) in bulky carbons, which possessed excellent electrocatalytic activity for the reduction of nitrite. the pronounced multi-electron catalytic ability was ascribed to the used hydrophobic ionic liquid which constructed an excellent charge-transfer bridge in the bulk of carbon paste electrode, thus facilitated the intake of electrons from reduced pmo12 mediators. in view of their prominent properties, the carbon paste electrode using ionic liquid binder and its bulk-modified electrode take on good prospects of the application in physical chemistry and electroanalytical chemistry fields. (c) 2005 elsevier b.v. all rights reserved.
WOS关键词	REDUCTION ; SOLVENT ; SENSORS ; 12-MOLYBDOPHOSPHATE ; 12-MOLYBDOSILICATE ; VOLTAMMETRY ; CHEMISTRY ; SURFACE ; CATION ; ANION
WOS研究方向	Electrochemistry
WOS类目	Electrochemistry
语种	英语
出版者	ELSEVIER SCIENCE INC
WOS记录号	WOS:000233720500031
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2377338
专题	中国科学院大学
通讯作者	Li, JH
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China
推荐引用方式 GB/T 7714	Liu, HT,He, P,Li, ZY,et al. An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties[J]. Electrochemistry communications,2005,7(12):1357-1363.
APA	Liu, HT.,He, P.,Li, ZY.,Sun, CY.,Shi, LH.,...&Li, JH.(2005).An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties.Electrochemistry communications,7(12),1357-1363.
MLA	Liu, HT,et al."An ionic liquid-type carbon paste polyoxometalate-modified electrode and its properties".Electrochemistry communications 7.12(2005):1357-1363.

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