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	One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran
	Xiang, Xiaomin1,2; Cui, Jinglei1,2; Ding, Guoqiang3; Zheng, Hongyan3; Zhu, Yulei1,3; Li, Yongwang1,3
刊名	Acs sustainable chemistry & engineering
	2016-09-01
卷号	4期号:9页码:4506-4510
关键词	Hy zeolite Gamma-butyrolactone Ht-cu/zno/al2o3 5-hydroxymethylfurfural Biomass
ISSN号	2168-0485
DOI	10.1021/acssuschemeng.6b01411
通讯作者	Zhu, yulei(zhuyulei@sxicc.ac.cn)
英文摘要	Selective conversion of fructose to fuels and fine chemicals is an important step for biomass utilization. in this paper, direct conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran was first realized over combined hy zeolite and inexpensive hydrotalcite (ht)-cu/zno/al2o3 in a fixed-bed reactor. the cooperative effect of hy zeolite and gamma-butyrolactone solvent facilitated the dehydration of fructose into 5-hydroxymethylfurfural. by adjusting the hydrogenation temperature for hmf over ht-cu/zno/al2o3 catalyst, high yields of 2,5-dihydroxymethylfuran (48.2%) at 140 degrees c and 2,5-dimethylfuran (40.6%) at 240 degrees c were obtained, respectively.
WOS关键词	SELECTIVE HYDROGENATION ; ZEOLITE CATALYST ; CU-CATALYSTS ; BIOMASS ; FUELS ; METAL ; HMF
WOS研究方向	Chemistry ; Engineering
WOS类目	Chemistry, Multidisciplinary ; Engineering, Chemical
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000382713100005
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2375670
专题	中国科学院大学
通讯作者	Zhu, Yulei
作者单位	1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, 27 South Taoyuan Rd, Taiyuan 030001, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Synfuels China Co Ltd, Taiyuan 030032, Peoples R China
推荐引用方式 GB/T 7714	Xiang, Xiaomin,Cui, Jinglei,Ding, Guoqiang,et al. One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran[J]. Acs sustainable chemistry & engineering,2016,4(9):4506-4510.
APA	Xiang, Xiaomin,Cui, Jinglei,Ding, Guoqiang,Zheng, Hongyan,Zhu, Yulei,&Li, Yongwang.(2016).One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran.Acs sustainable chemistry & engineering,4(9),4506-4510.
MLA	Xiang, Xiaomin,et al."One-step continuous conversion of fructose to 2,5-dihydroxymethylfuran and 2,5-dimethylfuran".Acs sustainable chemistry & engineering 4.9(2016):4506-4510.

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