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	A novel heterometallic baga coordination polymer based on the bifunctional ligand 2,5-pyridine dicarboxylic acid
	Cui, Hong-Hua1; Lin, Chen-Sheng1; Shen, Nan-Nan1,2; Huang, Xiao-Ying1
刊名	Inorganic chemistry communications
	2016-08-01
卷号	70页码:86-89
关键词	Heterometallic cps Luminescence P-block element Alkaline-earth metal
ISSN号	1387-7003
DOI	10.1016/j.inoche.2016.05.023
通讯作者	Huang, xiao-ying(xyhuang@fjirsm.ac.cn)
英文摘要	The first heterometallic baga coordination polymer (cp), namely [ba2ga2(pydc)(4)(oh)(2)(h2o)(2)]center dot 3h(2)o (1) (h(2)pydc = 2.5-pyridine dicarboxylic acid), has been successfully synthesized by the reaction of the bifunctional ligand h(2)pydc, bacl2 center dot 2h(2)o and ga2o3 under hydrothermal conditions. single-crystal x-ray diffraction analysis reveals that compound 1 features a three-dimensional (3d) network structure constructed from ga-2(oh)(2) dimers incorporated ba-pydc skeletons. luminescence measurements showed that 1 exhibited strong emission band centered at 412 nm ascribed to the emission of ligand-to-ligand charge transfer, which was confirmed by theoretical studies. (c) 2016 elsevier b.v. all rights reserved.
WOS关键词	METAL-ORGANIC FRAMEWORKS ; CRYSTAL-STRUCTURES ; CONNECTIVITY ; LUMINESCENCE ; CHAINS ; MOFS
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000380865300020
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2375157
专题	中国科学院大学
通讯作者	Huang, Xiao-Ying
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Cui, Hong-Hua,Lin, Chen-Sheng,Shen, Nan-Nan,et al. A novel heterometallic baga coordination polymer based on the bifunctional ligand 2,5-pyridine dicarboxylic acid[J]. Inorganic chemistry communications,2016,70:86-89.
APA	Cui, Hong-Hua,Lin, Chen-Sheng,Shen, Nan-Nan,&Huang, Xiao-Ying.(2016).A novel heterometallic baga coordination polymer based on the bifunctional ligand 2,5-pyridine dicarboxylic acid.Inorganic chemistry communications,70,86-89.
MLA	Cui, Hong-Hua,et al."A novel heterometallic baga coordination polymer based on the bifunctional ligand 2,5-pyridine dicarboxylic acid".Inorganic chemistry communications 70(2016):86-89.

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