QQ客服 官方微博 反馈留言

	[au(eta(2)- sn2sb2)(2)](3-): a mixed group 14/15 tetrahedral dimer bridged by au
	Pan Fu-Xing1,2; Li Lei-Jiao1; Sun Zhong-Ming1,3
刊名	Chinese journal of structural chemistry
	2016-07-01
卷号	35期号:7页码:1099-1106
关键词	Zintl cluster Dft calculations Gold Antimony
ISSN号	0254-5861
DOI	10.14102/j.cnki.0254-5861.2011-1125
通讯作者	Sun zhong-ming(szm@ciac.ac.cn)
英文摘要	A new ternary cluster anion [au(eta(2)-sn2sb2)(2)](3-) was synthesized and identified. the electronic structure of [au(eta(2)-sn2sb2)(2)](3-) was analyzed by means of dft calculations. the electronic energy and energy gap indicate that [au(eta(2)-sn2sb2)(2)](3-) features coplanar faces ausn2 in which gold is directly coordinated by four tin atoms. molecule orbital composition analysis indicates that d-orbital in au atom contributes to bonding. charge decomposition analysis (cda) shows that electron donation and back donation are the key factors forming planar conformation of au atom in [au(eta(2)-sn2sb2)(2)](3-) . meanwhile, the calculated mayer bond order indicates relatively weaker interactions between au and coordinated tetrahedral [sn2sb2](2-).
WOS关键词	LIQUID-AMMONIA ; ZINTL CLUSTERS ; INTERMETALLOID CLUSTERS ; CRYSTAL-STRUCTURES ; DENSITY FUNCTIONALS ; TRANSITION-ELEMENTS ; SOLUTION CHEMISTRY ; GAS-PHASE ; ANIONS ; TERNARY
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Inorganic & Nuclear ; Crystallography
语种	英语
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS记录号	WOS:000385766200015
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2374910
专题	中国科学院大学
通讯作者	Sun Zhong-Ming
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
推荐引用方式 GB/T 7714	Pan Fu-Xing,Li Lei-Jiao,Sun Zhong-Ming. [au(eta(2)- sn2sb2)(2)](3-): a mixed group 14/15 tetrahedral dimer bridged by au[J]. Chinese journal of structural chemistry,2016,35(7):1099-1106.
APA	Pan Fu-Xing,Li Lei-Jiao,&Sun Zhong-Ming.(2016).[au(eta(2)- sn2sb2)(2)](3-): a mixed group 14/15 tetrahedral dimer bridged by au.Chinese journal of structural chemistry,35(7),1099-1106.
MLA	Pan Fu-Xing,et al."[au(eta(2)- sn2sb2)(2)](3-): a mixed group 14/15 tetrahedral dimer bridged by au".Chinese journal of structural chemistry 35.7(2016):1099-1106.

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。