QQ客服 官方微博 反馈留言

	Single-molecule magnet behavior in an octanuclear dysprosium(iii) aggregate inherited from helical triangular dy-3 smm-building blocks
	Zhang, Li1,2; Zhang, Peng3; Zhao, Lang1; Wu, Jianfeng1,2; Guo, Mei1,2; Tang, Jinkui1
刊名	Dalton transactions
	2016
卷号	45期号:26页码:10556-10562
ISSN号	1477-9226
DOI	10.1039/c6dt01718e
通讯作者	Tang, jinkui(tang@ciac.ac.cn)
英文摘要	An unprecedented octanuclear dysprosium(iii) cluster with the formula [dy8l6(mu(3)-oh)(4)(mu(2)-ch3o)(2)-(ch3oh)(6)(h2o)(2)]center dot 6h(2)o center dot 10ch(3)oh center dot 2ch(3)cn (1) based on a nonlinearly tritopic aroylhydrazone ligand h3l has been isolated, realizing the successful linking of pairwise interesting triangular dy-3 smms. it is note-worthy that two enantiomers (lambda and delta configurations) individually behaving as a coordination-induced chirality presented in the dy-3 helicate are connected in the meso dy-8 cluster. remarkably, alternatingcurrent magnetic susceptibility measurements revealed that the dy-8 cluster shows typical smm behavior inherited from its dy-3 helical precursor. it is one of the rare polynuclear lnn smms (n > 7) under zero dc field.
WOS关键词	ION MAGNETS ; SOFT ACIDS ; RELAXATION ; COMPLEXES ; TRIANGLES ; LIGANDS ; DYNAMICS ; SYMMETRY ; EXCHANGE ; CLUSTER
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000379352900011
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2374637
专题	中国科学院大学
通讯作者	Tang, Jinkui
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rafe Earth Resource Utilizat, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Stuttgart, Inst Phys Chem, D-70569 Stuttgart, Germany
推荐引用方式 GB/T 7714	Zhang, Li,Zhang, Peng,Zhao, Lang,et al. Single-molecule magnet behavior in an octanuclear dysprosium(iii) aggregate inherited from helical triangular dy-3 smm-building blocks[J]. Dalton transactions,2016,45(26):10556-10562.
APA	Zhang, Li,Zhang, Peng,Zhao, Lang,Wu, Jianfeng,Guo, Mei,&Tang, Jinkui.(2016).Single-molecule magnet behavior in an octanuclear dysprosium(iii) aggregate inherited from helical triangular dy-3 smm-building blocks.Dalton transactions,45(26),10556-10562.
MLA	Zhang, Li,et al."Single-molecule magnet behavior in an octanuclear dysprosium(iii) aggregate inherited from helical triangular dy-3 smm-building blocks".Dalton transactions 45.26(2016):10556-10562.

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。