| Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds | |
| Huo, Jingfeng1; Xue, Yazhen1; Wang, Jianbo1,2 | |
| 刊名 | Chemical communications
 |
| 2018-11-07 | |
| 卷号 | 54期号:86页码:12266-12269 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c8cc07764a |
| 通讯作者 | Wang, jianbo(wangjb@pku.edu.cn) |
| 英文摘要 | A cu(i)-catalyzed aminoborylation reaction of styrenes is reported. in this transformation, diazo compounds are used as the electrophilic amination agent. the in situ generated benzylcopper species is trapped by the electrophilic nitrogen terminus of the diazo substrate to afford borylated hydrazones in a regioselective manner. |
| WOS关键词 | UNACTIVATED TERMINAL ALKENES ; AMINOBORATION ; INSERTION ; ESTERS ; ELECTROPHILES ; NITROGEN ; BONDS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000448501400029 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2373150 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huo, Jingfeng,Xue, Yazhen,Wang, Jianbo. Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds[J]. Chemical communications,2018,54(86):12266-12269. |
| APA | Huo, Jingfeng,Xue, Yazhen,&Wang, Jianbo.(2018).Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds.Chemical communications,54(86),12266-12269. |
| MLA | Huo, Jingfeng,et al."Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds".Chemical communications 54.86(2018):12266-12269. |
| 个性服务 |
| 查看访问统计 |
| 相关权益政策 |
| 暂无数据 |
| 收藏/分享 |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论