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	Shape-controlled synthesis of metal-organic frameworks with adjustable fenton-like catalytic activity
	Liu, Jiayi1,5; Li, Xuning1; Liu, Biao2; Zhao, Chunxiao1,4; Kuang, Zhichong1,5; Hu, Ruisheng4; Liu, Bin3; Ao, Zhimin2; Wang, Junhu1
刊名	Acs applied materials & interfaces
	2018-11-07
卷号	10期号:44页码:38051-38056
关键词	Secondary building units Shape-controlled Prussian blue analogue Dft calculation Fenton reaction
ISSN号	1944-8244
DOI	10.1021/acsami.8b12686
通讯作者	Liu, bin(liubin@ntu.edu.sg) ; Ao, zhimin(zhimin.ao@gdut.edu.cn) ; Wang, junhu(wangjh@dicp.ac.cn)
英文摘要	Controllable synthesis of metal-organic frameworks with well-defined morphology, composition, and size is of great importance toward understanding their structure-property relationship in various applications. herein, we demonstrate a general strategy to modulate the relative growth rate of the secondary building units (sbus) along different crystal facets for the synthesis of fe-co, mn0.5fe0.5-co, and mn-co prussian blue analogues (pbas) with tunable morphologies. the same growth rate of sbus along the {100}, {110}, and {111} surfaces at 0 degrees c results in the formation of spherical pba particles, while the lowest growth rate of sbus along the {100} surface resulting from the highest surface energy with increasing reaction temperature induces the formation of pba cubes. fenton reaction was used as the model reaction to probe the structure-catalytic activity relation for the as-synthesized catalysts. the cubic fe-co pba was found to exhibit the best catalytic performance with reaction rate constant 6 times higher than that of the spherical counterpart. via density functional theory calculations, the abundant enclosed {100} facets in cubic fe-co pba were identified to have the highest surface energy and favor high fenton reaction activity.
WOS关键词	PRUSSIAN BLUE ANALOGS ; POROUS COORDINATION POLYMERS ; BISPHENOL-A ; HYDROGEN STORAGE ; CO ; PEROXYMONOSULFATE ; DEGRADATION ; FE ; ACTIVATION ; MECHANISM
WOS研究方向	Science & Technology - Other Topics ; Materials Science
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000449887600031
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2373115
专题	大连化学物理研究所
通讯作者	Liu, Bin; Ao, Zhimin; Wang, Junhu
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 2.Guangdong Univ Technol, Sch Environm Sci & Engn, Inst Environm Hlth & Pollut Control, Guangzhou Key Lab Environm Catalysis & Pollut Con, Guangzhou 510006, Guangdong, Peoples R China 3.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore 4.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Jiayi,Li, Xuning,Liu, Biao,et al. Shape-controlled synthesis of metal-organic frameworks with adjustable fenton-like catalytic activity[J]. Acs applied materials & interfaces,2018,10(44):38051-38056.
APA	Liu, Jiayi.,Li, Xuning.,Liu, Biao.,Zhao, Chunxiao.,Kuang, Zhichong.,...&Wang, Junhu.(2018).Shape-controlled synthesis of metal-organic frameworks with adjustable fenton-like catalytic activity.Acs applied materials & interfaces,10(44),38051-38056.
MLA	Liu, Jiayi,et al."Shape-controlled synthesis of metal-organic frameworks with adjustable fenton-like catalytic activity".Acs applied materials & interfaces 10.44(2018):38051-38056.

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