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Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides
Hu, Panjie1; Zhang, Ying1; Liu, Bingxian1; Li, Xingwei1,2
刊名Organic chemistry frontiers
2018-11-21
卷号5期号:22页码:3263-3266
ISSN号2052-4129
DOI10.1039/c8qo00861b
通讯作者Liu, bingxian(liubx1120@163.com) ; Li, xingwei(xwli@dicp.ac.cn)
英文摘要Rhodium(iii)-catalyzed regio- and chemoselective [5 + 2] annulation between n-(cyanoacetyl)indolines and sulfoxonium ylides has been realized, leading to efficient construction of seven-membered rings under mild conditions. this reaction proceeded via c-h activation with sulfoxonium ylides as carbene synthons.
WOS关键词CASCADE OXIDATIVE ANNULATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; BOND FUNCTIONALIZATION ; INTERNAL ALKYNES ; ACTIVATION ; ARENES ; DERIVATIVES ; CYCLIZATION ; CLEAVAGE ; KETONES
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000449412800010
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2373088
专题大连化学物理研究所
通讯作者Liu, Bingxian; Li, Xingwei
作者单位1.Henan Normal Univ, Henan Key Lab Organ Funct Mol & Drug Innovat, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Hu, Panjie,Zhang, Ying,Liu, Bingxian,et al. Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides[J]. Organic chemistry frontiers,2018,5(22):3263-3266.
APA Hu, Panjie,Zhang, Ying,Liu, Bingxian,&Li, Xingwei.(2018).Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides.Organic chemistry frontiers,5(22),3263-3266.
MLA Hu, Panjie,et al."Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides".Organic chemistry frontiers 5.22(2018):3263-3266.
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