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	Constructing mononuclear palladium catalysts by precoordination/solvothermal polymerization: recyclable catalyst for regioselective oxidative heck reactions
	Li, Wen-Hao1; Li, Cun-Yao2,3; Xiong, Huan-Yan1; Liu, Yang4; Huang, Wen-Yong1; Ji, Guang-Jun2,3; Jiang, Zheng4; Tang, Hai-Tao1; Pan, Ying-Ming1; Ding, Yun-Jie2,3
刊名	Angewandte chemie-international edition
	2019-02-18
卷号	58期号:8页码:2448-2453
关键词	Heck reaction Heterogeneous catalysis N-heterocyclic carbenes Palladium Regioselectivity
ISSN号	1433-7851
DOI	10.1002/anie.201814493
通讯作者	Tang, hai-tao(httang@gxnu.edu.cn) ; Pan, ying-ming(panym@mailbox.gxnu.edu.cn) ; Ding, yun-jie(dyj@dicp.ac.cn)
英文摘要	Heterogeneous, metal, single-site catalysts often exhibit higher catalytic performance than other catalysts because of their maximized atom efficiency of 100 %. reported herein is a precoordination/solvothermal polymerization strategy to fabricate a stable mononuclear pd-metalized porous organic polymer catalyst (pd@pop). pd@pop was easy to use in regioselective organic reactions because the internal structure of this pd@pop can be easily modified. the catalyst was used to solve the intractable regioselectivity problems of heck reactions. pd@pop-9 can efficiently activate the ends of olefins, thereby leading to high selectivity for substitution at the external position. to understand the reason underlying the high selectivity and activity of the catalyst, the systemic characterization of pd@pop-9 and density-functional theory calculations were conducted. this heck reaction is the first to be catalyzed by a recyclable mononuclear metal catalyst with unprecedented catalytic activity and regioselectivity.
WOS关键词	HIGH SELECTIVITY ; ACTIVATION ; OLEFINS ; REACTIVITY ; CONVERSION ; LIGAND ; OXYGEN
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000458417700047
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2372836
专题	大连化学物理研究所
通讯作者	Tang, Hai-Tao; Pan, Ying-Ming; Ding, Yun-Jie
作者单位	1.Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, State Key Lab Chem & Mol Engn Med Resources, Guilin 541004, Peoples R China 2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China
推荐引用方式 GB/T 7714	Li, Wen-Hao,Li, Cun-Yao,Xiong, Huan-Yan,et al. Constructing mononuclear palladium catalysts by precoordination/solvothermal polymerization: recyclable catalyst for regioselective oxidative heck reactions[J]. Angewandte chemie-international edition,2019,58(8):2448-2453.
APA	Li, Wen-Hao.,Li, Cun-Yao.,Xiong, Huan-Yan.,Liu, Yang.,Huang, Wen-Yong.,...&Ding, Yun-Jie.(2019).Constructing mononuclear palladium catalysts by precoordination/solvothermal polymerization: recyclable catalyst for regioselective oxidative heck reactions.Angewandte chemie-international edition,58(8),2448-2453.
MLA	Li, Wen-Hao,et al."Constructing mononuclear palladium catalysts by precoordination/solvothermal polymerization: recyclable catalyst for regioselective oxidative heck reactions".Angewandte chemie-international edition 58.8(2019):2448-2453.

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