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	An organic-base catalyzed asymmetric 1,4-addition of tritylthiol to in situ generated aza-o-quinone methides at the h2o/dcm interface
	Liu, Xianghui1,2; Wang, Kai1,2; Guo, Wengang1; Liu, Yan1; Li, Can1
刊名	Chemical communications
	2019-03-04
卷号	55期号:18页码:2668-2671
ISSN号	1359-7345
DOI	10.1039/c8cc09382b
通讯作者	Liu, yan(yanliu503@dicp.ac.cn) ; Li, can(canli@dicp.ac.cn)
英文摘要	Based on an efficient method for in situ generation of n-o-qm species in the presence of a base, enantioselective catalytic conjugated additions of tritylthiol to in situ generated n-o-qms are reported. acid-base bifunctional organocatalyst 4c (10 mol%) enables these transformations with high stereoselectivities (up to 94% ee) using h2o/dcm as a solvent under mild conditions.
WOS关键词	ENANTIOSELECTIVE 4+2 CYCLOADDITION ; HYDROXYBENZYL ALCOHOLS ; ORTHO-XYLYLENES ; ACID CATALYSIS ; ROUTE ; TRIARYLMETHANES ; ANNULATION ; ENAMIDES ; INDOLES ; ACCESS
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000459737100017
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2372787
专题	大连化学物理研究所
通讯作者	Liu, Yan; Li, Can
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Liu, Xianghui,Wang, Kai,Guo, Wengang,et al. An organic-base catalyzed asymmetric 1,4-addition of tritylthiol to in situ generated aza-o-quinone methides at the h2o/dcm interface[J]. Chemical communications,2019,55(18):2668-2671.
APA	Liu, Xianghui,Wang, Kai,Guo, Wengang,Liu, Yan,&Li, Can.(2019).An organic-base catalyzed asymmetric 1,4-addition of tritylthiol to in situ generated aza-o-quinone methides at the h2o/dcm interface.Chemical communications,55(18),2668-2671.
MLA	Liu, Xianghui,et al."An organic-base catalyzed asymmetric 1,4-addition of tritylthiol to in situ generated aza-o-quinone methides at the h2o/dcm interface".Chemical communications 55.18(2019):2668-2671.

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