Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates
	Meng, Chun-Yan; Liang, Xiao; Wei, Kun; Yang, Yu-Rong
刊名	ORGANIC LETTERS
	2019-02-01
卷号	21 期号:3 页码:840-843
ISSN号	1523-7060
英文摘要	Ir-catalyzed enantioselective allylic alkylation of branched racemic allylic alcohols with malonates is described. Enabled by Carreira's chiral Ir/(P, olefin) complex, the method described allows allylic substitution with various aromatic alcohols and malonates with excellent enantioselectivity. The malonates could be used directly as efficient nucleophiles without the need of preactivation.
资助项目	Key Research Program of the Frontier Sciences of the CAS[QYZDB-SSW-SMC026] ; NSFC[21672224] ; NSFC[21472200] ; Government of Yunnan Province[2017FA002]
语种	英语
资助机构	Key Research Program of the Frontier Sciences of the CAS ; NSFC ; Government of Yunnan Province
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/64241]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
通讯作者	Wei, Kun; Yang, Yu-Rong
作者单位	Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China
推荐引用方式 GB/T 7714	Meng, Chun-Yan,Liang, Xiao,Wei, Kun,et al. Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates[J]. ORGANIC LETTERS,2019,21(3):840-843.
APA	Meng, Chun-Yan,Liang, Xiao,Wei, Kun,&Yang, Yu-Rong.(2019).Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates.ORGANIC LETTERS,21(3),840-843.
MLA	Meng, Chun-Yan,et al."Enantioselective Ir-Catalyzed Allylic Alkylation of Racemic Allylic Alcohols with Malonates".ORGANIC LETTERS 21.3(2019):840-843.