Facile and environmentally friendly synthesis of six heterometallic dumbbell-shaped MII5LnIII4 (M = Co, Ni; Ln = Eu, Gd, Dy) clusters as cryogenic magnetic coolants and molecular magnets

	Facile and environmentally friendly synthesis of six heterometallic dumbbell-shaped MII5LnIII4 (M = Co, Ni; Ln = Eu, Gd, Dy) clusters as cryogenic magnetic coolants and molecular magnets
	Tao, Jun; Shao, Feng; Zhuang, Jia-Jia; Chen, Ming-Guang; Wang, Ning; Shi, Hai-Yan; Tong, Jia-Ping; Luo, Gang; Zheng, Lan-Sun
刊名	DALTON TRANSACTIONS
	2018
文献子类	期刊论文
英文摘要	Six analogous dumbbell-shaped 3d-4f complexes MII5LnIII4 were obtained by the reaction of Ln(NO3)(3) (Ln = Eu, Gd, Dy) and M(OAc)(2) (M = Co, Ni) without any other organic ligands, and M5Gd4 exhibited a large magnetocaloric effect (-S-m = 31.0, 37.3 J kg(-1) K-1 for Co5Gd4 and Ni5Gd4 respectively), while M5Dy4 and Co5Eu4 showed single molecule magnet behaviour. To the best of our knowledge, Co5Eu4 is the first Eu-based cluster to display single molecule magnet behaviour (U-eff = 16.4 K).
语种	英语
内容类型	期刊论文
源URL	[http://ir.siat.ac.cn:8080/handle/172644/14882]
专题	深圳先进技术研究院_其他
推荐引用方式 GB/T 7714	Tao, Jun,Shao, Feng,Zhuang, Jia-Jia,et al. Facile and environmentally friendly synthesis of six heterometallic dumbbell-shaped MII5LnIII4 (M = Co, Ni; Ln = Eu, Gd, Dy) clusters as cryogenic magnetic coolants and molecular magnets[J]. DALTON TRANSACTIONS,2018.
APA	Tao, Jun.,Shao, Feng.,Zhuang, Jia-Jia.,Chen, Ming-Guang.,Wang, Ning.,...&Zheng, Lan-Sun.(2018).Facile and environmentally friendly synthesis of six heterometallic dumbbell-shaped MII5LnIII4 (M = Co, Ni; Ln = Eu, Gd, Dy) clusters as cryogenic magnetic coolants and molecular magnets.DALTON TRANSACTIONS.
MLA	Tao, Jun,et al."Facile and environmentally friendly synthesis of six heterometallic dumbbell-shaped MII5LnIII4 (M = Co, Ni; Ln = Eu, Gd, Dy) clusters as cryogenic magnetic coolants and molecular magnets".DALTON TRANSACTIONS (2018).