High-Performance Cathode Based on Self-Templated 3D Porous Microcrystalline Carbon with Improved Anion Adsorption and Intercalation | |
Ge Zhang; Xuewu Ou; Chunyu Cui; Jianmin Ma; Jinghai Yang; Yongbing Tang | |
刊名 | Advanced Functional Materials |
2018 | |
文献子类 | 期刊论文 |
英文摘要 | Dual-ion batteries (DIBs) have attracted much attention due to their advantages of low cost and especially environmental friendliness. However, the capacities of most DIBs are still unsatisfied (≈100 mAh g−1) ascribed to the limited capacity of anions intercalation for conventional graphite cathode. In this study, 3D porous microcrystalline carbon (3D-PMC) was designed and synthesized via a self-templated growth approach, and when used as cathode for a DIB, it allows both intercalation and adsorption of anions. The microcrystalline carbon is beneficial to obtain capacity originated from anions intercalation, and the 3D porous structure with a certain surface area contributes to anions adsorption capacity. With the synergistic effect, this 3D-PMC is utilized as cathode and tin as anode for a sodium-based DIB, which has a high capacity of 168.0 mAh g−1 at 0.3 A g−1, among the best values of reported DIBs so far. This cell also exhibits long-term cycling stability with a capacity retention of ≈70% after 2000 cycles at a high current rate of 1 A g−1. It is believed that this work will provide a strategy to develop high-performance cathode materials for DIBs. |
URL标识 | 查看原文 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.siat.ac.cn:8080/handle/172644/13553] |
专题 | 深圳先进技术研究院_集成所 |
推荐引用方式 GB/T 7714 | Ge Zhang,Xuewu Ou,Chunyu Cui,et al. High-Performance Cathode Based on Self-Templated 3D Porous Microcrystalline Carbon with Improved Anion Adsorption and Intercalation[J]. Advanced Functional Materials,2018. |
APA | Ge Zhang,Xuewu Ou,Chunyu Cui,Jianmin Ma,Jinghai Yang,&Yongbing Tang.(2018).High-Performance Cathode Based on Self-Templated 3D Porous Microcrystalline Carbon with Improved Anion Adsorption and Intercalation.Advanced Functional Materials. |
MLA | Ge Zhang,et al."High-Performance Cathode Based on Self-Templated 3D Porous Microcrystalline Carbon with Improved Anion Adsorption and Intercalation".Advanced Functional Materials (2018). |
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