A porous Bronsted superacid as an efficient and durable solid catalyst

doi:10.1039/c8ta06516k

	A porous Bronsted superacid as an efficient and durable solid catalyst
	Xiao, Feng-Shou 4; Ma, Shengqian 1; Meng, Xiangju 4; Zheng, Anmin 2; Sun, Yinyong 2; Aguila, Briana 1; Yi, Xianfeng 2; Leng, Kunyue 3; Hu, Kewei 4; Sun, Qi 4
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2018-10-14
卷号	6 期号:38 页码:18712-18719
ISSN号	2050-7488
DOI	10.1039/c8ta06516k
英文摘要	The development of catalysts able to assist industrial chemical transformations is a topic of high importance. In view of the versatile catalytic capabilities of acid catalysts, extensive research efforts are being made to develop porous superacid materials with a high density of accessible active sites to replace molecular acid catalysts. Herein, we report the rational development of a porous Bronsted superacid by combining important elements that target high strength acidity into one material, as demonstrated by grafting the sulfonic acid group onto a highly fluorinated porous framework, where the acid strength and stability are greatly enhanced by an electron-withdrawing environment provided by the polymer backbone, reminiscent of that seen in Nafion (R) resin. In addition, the densely arranged acid groups that are confined in the three-dimensional nanospace facilitate the transfer of hydrons, thereby further increasing the acidity. By virtue of the pore structure and strong acidity, this system exhibits excellent performance for a wide range of reactions, far outperforming commercial acid resins under repeated batch and flow reaction conditions. Our findings demonstrate how this synthetic approach may instruct the future design of heterogeneous acid catalysts with advantageous reaction capabilities and stability.
资助项目	National Natural Science Foundation of China[21720102001] ; National Natural Science Foundation of China[21333009] ; National Natural Science Foundation of China[21422306]
WOS关键词	CONJUGATED MICROPOROUS POLYMERS ; ACID CATALYST ; ORGANIC POLYMERS ; GREEN ; NMR ; ESTERIFICATION ; THRESHOLD ; ACYLATION ; STRENGTH ; SILICAS
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000451380800043
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/13517]
专题	中国科学院武汉物理与数学研究所
通讯作者	Xiao, Feng-Shou; Sun, Qi
作者单位	1.Univ S Florida, Dept Chem, 4202 E Fowler Ave, Tampa, FL 33620 USA 2.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China 3.Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China 4.Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China
推荐引用方式 GB/T 7714	Xiao, Feng-Shou,Ma, Shengqian,Meng, Xiangju,et al. A porous Bronsted superacid as an efficient and durable solid catalyst[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(38):18712-18719.
APA	Xiao, Feng-Shou.,Ma, Shengqian.,Meng, Xiangju.,Zheng, Anmin.,Sun, Yinyong.,...&Sun, Qi.(2018).A porous Bronsted superacid as an efficient and durable solid catalyst.JOURNAL OF MATERIALS CHEMISTRY A,6(38),18712-18719.
MLA	Xiao, Feng-Shou,et al."A porous Bronsted superacid as an efficient and durable solid catalyst".JOURNAL OF MATERIALS CHEMISTRY A 6.38(2018):18712-18719.