| Novel Ru-fluoridated apatite catalyst with nano-rod morphology for highly efficient aerobic oxidation of alcohols | |
| Zhang YJ(张彦杰) ; Wang JH(王军虎) ; Yin J(尹杰) ; Zhao KF(赵昆峰) ; Jin ZZ(金长子) ; Zhang T(张涛) | |
| 2010-07-18 | |
| 会议名称 | sixth tokyo conference on advanced catalytic science and technology&fifth asia pacific congress on catalysis\ |
| 会议日期 | 2010-7-18 |
| 会议地点 | 日本 |
| 页码 | 79/2 |
| 通讯作者 | 王军虎 |
| 中文摘要 | recyclable ru-fluoridated apatite catalyst with nano-rod morphology, newly developed by chemical precipitation and ion change methods under mild conditions, has demonstrated highly efficient aerobic oxidation of benzyl alcohol at 353 k with good selectivity (>99%) and excellent reaction yield (tof: ~202 h-1). the enhanced activity was preliminarily ascribed to the more amounts of small hydrated ru3+-oxide nanoparticles existing in the surface of fluoridated apatite compared to ruhap because of the well-known low solubility and high acid fastness of fluoridated apatite compared to hap. keywords: fluoridated apatite; ruthenium; aerobic oxidation of alcohol. |
| 会议主办者 | catalysis society of japan |
| 学科主题 | 物理化学 |
| 语种 | 中文 |
| 内容类型 | 会议论文 |
| 源URL | [http://159.226.238.44/handle/321008/114158]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhang YJ,Wang JH,Yin J,et al. Novel Ru-fluoridated apatite catalyst with nano-rod morphology for highly efficient aerobic oxidation of alcohols[C]. 见:sixth tokyo conference on advanced catalytic science and technology&fifth asia pacific congress on catalysis\. 日本. 2010-7-18. |
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