Carboxymethyl chitosan/poly(ethylene oxide) water soluble binder: Challenging application for 5 V LiNi0.5Mn1.5O4 cathode | |
Zhong, Haoxing1; Lu, Jidian2; He, Aiqin2; Sun, Minghao1,3; He, Jiarong1,3; Zhang, Lingzhi1 | |
刊名 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY |
2017-08-01 | |
卷号 | 33期号:8页码:763-767 |
关键词 | Carboxymethyl Chitosan Poly (Ethylene Oxide) Water Soluble Binder Lini0.5mn1.5o4 Lithium Ion Battery |
DOI | 10.1016/j.jmst.2017.01.019 |
文献子类 | Article |
英文摘要 | Carboxymethyl chitosan/poly (ethylene oxide) (CCTS/PEO) composite is firstly reported as a water soluble binder for the application of 5 V LiNi0.5Mn1.5O4 cathode in Li-ion batteries. Both CCTS and PEO show a high electrochemical oxidation potential of above 5.0 V (vs. Li/Li+). The electrochemical performances of LiNi0.5Mn1.5O4 (LNMO) cathodes with CCTS/PEO composite binders of different mass rates are investigated, it is found that LiNi0.5Mn1.5O4 cathode with an optimized CCTS/PEO (85/15, w/w) composite exhibits a slightly better cycling performance than that of polyvinylidene fluoride (PVDF), retaining 81.4% capacity as compared with 79.8% for PVDF at 0.5C rate after 200 cycles. LNMO with PEO/CCTS (85/15, w/w) exhibited the better rate capability than that of PVDF. These results demonstrate that CCTS/PEO composite can be potentially used as a water-soluble binder for 5 V LNMO cathode. (C) 2017 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
WOS关键词 | LITHIUM-ION BATTERIES ; NEGATIVE ELECTRODES ; ELECTROCHEMICAL PROPERTIES ; POLYACRYLIC-ACID ; LIFEPO4 CATHODE ; POLYMER BLENDS ; CHITOSAN ; PERFORMANCE ; ANODES ; MORPHOLOGY |
语种 | 英语 |
WOS记录号 | WOS:000410666000001 |
资助机构 | K.C. Wong Education Foundation ; National Natural Science Foundation of China(21573239) ; Science & Technology project of Guangdong province(2014TX01N014/2015B010135008) ; Guangzhou Municipal Project for Science Technology(201509010018) ; Natural Science Foundation of Guangdong Province(2015A030313721) |
内容类型 | 期刊论文 |
源URL | [http://ir.giec.ac.cn/handle/344007/16299] |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 2.Guangzhou Lithium Force Energy Technol Co Ltd, Guangzhou 510730, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Zhong, Haoxing,Lu, Jidian,He, Aiqin,et al. Carboxymethyl chitosan/poly(ethylene oxide) water soluble binder: Challenging application for 5 V LiNi0.5Mn1.5O4 cathode[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2017,33(8):763-767. |
APA | Zhong, Haoxing,Lu, Jidian,He, Aiqin,Sun, Minghao,He, Jiarong,&Zhang, Lingzhi.(2017).Carboxymethyl chitosan/poly(ethylene oxide) water soluble binder: Challenging application for 5 V LiNi0.5Mn1.5O4 cathode.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,33(8),763-767. |
MLA | Zhong, Haoxing,et al."Carboxymethyl chitosan/poly(ethylene oxide) water soluble binder: Challenging application for 5 V LiNi0.5Mn1.5O4 cathode".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 33.8(2017):763-767. |
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