Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst

doi:10.1016/j.catcom.2017.05.014

CORC > 广州能源研究所 > 中国科学院广州能源研究所 > 中国科学院广州能源研究所

	Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst
	Sun, Fei 1,2; Chen, Lungang 1; Weng, Yujing 1; Wang, Tiejun 1; Qiu, Songbai 1; Li, Quanxin 3; Wang, Chenguang 1; Zhang, Qi 1; Ma, Longlong 1
刊名	CATALYSIS COMMUNICATIONS
	2017-08-01
卷号	99 页码:30-33
关键词	Biomass Hydrodeoxygenation Carbon Nanotubes Hydrocarbon Fuels
DOI	10.1016/j.catcom.2017.05.014
文献子类	Article
英文摘要	The hydrodeoxygenation (HDO) of sorbitol in aqueous medium was performed over CNT supported Ru-Mo bimetallic catalyst. Compared with Ru-Mo/AC, Ru-Mo/CNT showed higher yield and selectivity towards C5/C6 alkanes due to the higher relative rate of C-O vs. C-C bond cleavage of sorbitol. Based on TEM, XPS and H-2-TPR characterizations, the role of CNT in HDO reaction was studied to clarify the likely reasons for the selective C-O vs. C-C bond cleavage. It is suggested that an increase concentration of MoOx (x < 3) species and a smaller metal particle size in the Ru-Mo/CNT catalyst are key factors for the improvement of HDO performance.
WOS关键词	CARBON NANOTUBES ; PHASE HYDRODEOXYGENATION ; LIGNOCELLULOSIC BIOMASS ; EFFICIENT CATALYSTS ; PROPANOIC ACID ; PARTICLE-SIZE ; CONVERSION ; ALKANES ; SORBITOL ; NANOPARTICLES
语种	英语
WOS记录号	WOS:000405973200007
资助机构	National Natural Science Foundation of China(51476176 ; Key Project of National Natural Science Foundation of China(51536009) ; STS Program of Chinese Academy of Sciences(KFJ-EW-STS-138) ; Science and Technology Program of Guangdong Province(2014A010106022) ; 5161101344)
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/14178]
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Univ Sci & Technol China, Sch Chem & Mat Sci, Hefei 230000, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Sun, Fei,Chen, Lungang,Weng, Yujing,et al. Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst[J]. CATALYSIS COMMUNICATIONS,2017,99:30-33.
APA	Sun, Fei.,Chen, Lungang.,Weng, Yujing.,Wang, Tiejun.,Qiu, Songbai.,...&Ma, Longlong.(2017).Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst.CATALYSIS COMMUNICATIONS,99,30-33.
MLA	Sun, Fei,et al."Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst".CATALYSIS COMMUNICATIONS 99(2017):30-33.