p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural

doi:10.1039/c7ra03155f

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	p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural
	Li, Wenzhi 1; Zhang, Tingwei 1; Xin, Haosheng 2; Su, Mingxue 3; Ma, Longlong4 ; Jameel, Hason 5; Chang, Hou-min 5; Pei, Gang 1
刊名	RSC ADVANCES
	2017
卷号	7 期号:44 页码:27682-27688
DOI	10.1039/c7ra03155f
文献子类	Article
英文摘要	A novel solid p-hydroxybenzenesulfonic acid-formaldehyde resin (SPFR) was prepared via a straightforward hydrothermal method. The catalytic properties of SPFR solid acids were evaluated in the dehydration reaction of fructose and glucose to 5-hydroxymethylfurfural (HMF). SEM, TEM, N-2 adsorption-desorption, elemental analysis (EA), thermogravimetric analysis (TGA), and FT-IR were used to explore the effects of catalyst structure and composition on the HMF preparation from fructose. The effects of reaction time and temperature on the dehydration of fructose and glucose were also investigated. An HMF yield as high as 82.6% was achieved from fructose at 140 degrees C after 30 min, and 33.0% was achieved from glucose at 190 degrees C in 30 min. Furthermore, the recyclability of SPFR for the HMF production from fructose in 5 cycles was good.
WOS关键词	GAMMA-VALEROLACTONE ; IONIC LIQUID ; CATALYTIC CONVERSION ; BIPHASIC SYSTEM ; LEVULINIC ACID ; MCM-41 SILICA ; LEWIS-ACID ; DEHYDRATION ; BIOMASS ; CHITOSAN
语种	英语
WOS记录号	WOS:000402166600059
资助机构	State Key Program of the National Natural Science Foundation of China(51536009) ; National Key Technology R&D Program of China(2015BAD15B06) ; Science and Technological Fund of the Anhui Province(1508085J01)
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/14133]
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 2.Anhui Jianzhu Univ, Inst Mat & Chem Engn, Hefei 230022, Peoples R China 3.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 5.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA
推荐引用方式 GB/T 7714	Li, Wenzhi,Zhang, Tingwei,Xin, Haosheng,et al. p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural[J]. RSC ADVANCES,2017,7(44):27682-27688.
APA	Li, Wenzhi.,Zhang, Tingwei.,Xin, Haosheng.,Su, Mingxue.,Ma, Longlong.,...&Pei, Gang.(2017).p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural.RSC ADVANCES,7(44),27682-27688.
MLA	Li, Wenzhi,et al."p-Hydroxybenzenesulfonic acid-formaldehyde solid acid resin for the conversion of fructose and glucose to 5-hydroxymethylfurfural".RSC ADVANCES 7.44(2017):27682-27688.