In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst

doi:10.1016/j.fuproc.2016.08.018

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	In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst
	Xu, Ying1,2,3 ; Li, Yanbin 1; Wang, Congwei1,2,3 ; Wang, Chenguang 1,2,3; Ma, Longlong1,2,3 ; Wang, Tiejun1,2,3 ; Zhang, Xinghua1,2,3 ; Zhang, Qi1,2,3
刊名	FUEL PROCESSING TECHNOLOGY
	2017-06-15
卷号	161 页码:226-231
关键词	Bio-oil In-situ Hydrogenation Model Compounds Ni-base Catalyst Cmk-3
DOI	10.1016/j.fuproc.2016.08.018
文献子类	Article
英文摘要	Ni/CMK-3 catalyst, the mesoporous carbon material loading Ni activity, was prepared and used in the in-situ hydrogenation of mixed model compounds (including acetone, acetic acid, furfural, o-cresol, ethanediol and water) of bio-oil (MCB) and actual bio-oil in this paper. The effects of hydrogen donors, solvents and the dosages of catalyst were all investigated in the in-situ hydrogenation process. The results showed that the hydrogen donor of methanol, ethanol and formic acid could all provide hydrogen for the in-situ hydrogenation but the product distributions of bio-oils were different after in-situ hydrogenation. Using alcohols as hydrogen donors, esterification reaction happened between the hydrogen donors and acetic acid. The formic acid could promote the phenols conversion but the conversion of acetic acid was restrained. When the radio of water and methanol was 10:3 and 10:5, most of ketones and aldehydes in the raw bio-oil converted to alcohols and the conversion of acids and phenols was beyond 50%. The contents of alcohols and esters in raw bio-oil increased from 18.52% to 51.14% and 48.21%. (C) 2016 Elsevier B.V. All rights reserved.
WOS关键词	FAST PYROLYSIS ; PHENOLIC-COMPOUNDS ; NI CATALYST ; HYDRODEOXYGENATION ; ESTERIFICATION ; CONVERSION ; CARBON ; HYDROCARBONS ; ALCOHOLS ; QUALITY
语种	英语
WOS记录号	WOS:000401047600027
资助机构	Natural Science Foundation of China(51476178) ; Science and Technology Plan Key Project in Guangdong Province of China(2014A010106019) ; Youth Innovation Promotion Association CAS
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/14130]
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Xu, Ying,Li, Yanbin,Wang, Congwei,et al. In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst[J]. FUEL PROCESSING TECHNOLOGY,2017,161:226-231.
APA	Xu, Ying.,Li, Yanbin.,Wang, Congwei.,Wang, Chenguang.,Ma, Longlong.,...&Zhang, Qi.(2017).In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst.FUEL PROCESSING TECHNOLOGY,161,226-231.
MLA	Xu, Ying,et al."In-situ hydrogenation of model compounds and raw bio-oil over Ni/CMK-3 catalyst".FUEL PROCESSING TECHNOLOGY 161(2017):226-231.