Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst

doi:10.1063/1674-0068/29/cjcp1603062

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	Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst
	Tang, Wen-wu 1,3; Zhang, Xing-hua2,3 ; Zhang, Qi2,3 ; Wang, Tie-jun2,3 ; Ma, Long-long2,3
刊名	CHINESE JOURNAL OF CHEMICAL PHYSICS
	2016-10-01
卷号	29 期号:5 页码:617-622
关键词	Anisole Hydrodeoxygenation Ni/alpha-al2o3 Hydrocarbons
DOI	10.1063/1674-0068/29/cjcp1603062
文献子类	Article
英文摘要	Ni-based catalysts supported on different supports (alpha-Al2O3, gamma-Al2O3, SiO2, TiO2, and ZrO2) were prepared by impregnation. Effects of supports on catalytic performance were tested using hydrodeoxygenation reaction (HDO) of anisole as model reaction. Ni/alpha-Al2O3 was found to be the highest active catalyst for HDO of anisole. Under the optimal conditions, the anisole conversion is 93.25% and the hydrocarbon yield is 90.47%. Catalyst characterization using H-2-TPD method demonstrates that Ni/alpha-Al2O3 catalyst possesses more amount of active metal Ni than those of other investigated catalysts, which can enhance the catalytic activity for hydrogenation. Furthermore, it is found that the Ni/alpha-Al2O3 catalyst has excellent repeatability, and the carbon deposited on the surface of catalyst is negligible.
WOS关键词	LIGNIN DEPOLYMERIZATION ; PHENOLIC-COMPOUNDS ; AQUEOUS-PHASE ; BIO-OIL ; EFFICIENT ; GUAIACOL ; DECOMPOSITION ; HYDROCARBONS ; VALORIZATION ; CONVERSION
语种	英语
WOS记录号	WOS:000388063400015
资助机构	National Natural Science Foundation of China(51576198) ; National Key Technology RD Program(2014BAD02B01) ; Youth Innovation Promotion Association of Chinese Academy of Sciences(2015288)
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/13975]
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Tang, Wen-wu,Zhang, Xing-hua,Zhang, Qi,et al. Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2016,29(5):617-622.
APA	Tang, Wen-wu,Zhang, Xing-hua,Zhang, Qi,Wang, Tie-jun,&Ma, Long-long.(2016).Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst.CHINESE JOURNAL OF CHEMICAL PHYSICS,29(5),617-622.
MLA	Tang, Wen-wu,et al."Hydrodeoxygenation of Anisole over Ni/alpha-Al2O3 Catalyst".CHINESE JOURNAL OF CHEMICAL PHYSICS 29.5(2016):617-622.