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Ordered entanglement in actinide-organic coordination polymers
Mei, Lei1; Shi, Wei-qun1; Chai, Zhi-fang1,2,3
刊名Bulletin of the chemical society of japan
2018-04-01
卷号91期号:4页码:554-562
ISSN号0009-2673
DOI10.1246/bcsj.20170418
通讯作者Shi, wei-qun(shiwq@ihep.ac.cn)
英文摘要Entangled structures in actinide-organic hybrid materials featured by intertwining between isolated motifs show promising potential in the application of different fields, such as radionuclide separation, radiation detection, photocatalysis and smart materials. since how the individual motifs are entangled in combination of molecular structures of the structural units and topology of the individual motifs contributes most to the properties of actinide entangled materials, it is of significance to summarize and analyze these entanglements with diverse topologies. for this contribution, we will summarize all the entanglements in the reported actinide-organic entangled structures by classifying them according to the diverse catalogues of individual motifs and entangled patterns between them, among which are included all these intriguing types of entanglement in different seperate sections: 1) polyrotaxanes; 2) parallel interpenetration (int) and polycatenation (p-cat and i-cat); and 3) borromean ring (br). this work is aimed at figuring out some clues on design principles of actinide-organic entangled structures, the underlying rules of ordered entanglement and driving forces behind from our perspective so as to provide some valuable principles guiding the assembly process of entangled structures for reference and help to achieve the controlled syntheses of actinide compounds of interest in the future.
WOS关键词URANYL-ION COMPLEXES ; SUPRAMOLECULAR INCLUSION ; STRUCTURAL REGULATION ; MOLECULAR DEVICES ; FRAMEWORKS ; CHEMISTRY ; DESIGN ; POLYROTAXANES ; LUMINESCENCE ; PERSPECTIVES
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者CHEMICAL SOC JAPAN
WOS记录号WOS:000430096000007
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2178124
专题高能物理研究所
通讯作者Shi, Wei-qun
作者单位1.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China
2.Soochow Univ, Sch Radiol & Interdisciplinary Sci, Suzhou 215123, Peoples R China
3.Soochow Univ, Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, Suzhou 215123, Peoples R China
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GB/T 7714
Mei, Lei,Shi, Wei-qun,Chai, Zhi-fang. Ordered entanglement in actinide-organic coordination polymers[J]. Bulletin of the chemical society of japan,2018,91(4):554-562.
APA Mei, Lei,Shi, Wei-qun,&Chai, Zhi-fang.(2018).Ordered entanglement in actinide-organic coordination polymers.Bulletin of the chemical society of japan,91(4),554-562.
MLA Mei, Lei,et al."Ordered entanglement in actinide-organic coordination polymers".Bulletin of the chemical society of japan 91.4(2018):554-562.
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