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Selective hydrogenation of unsaturated aldehydes over pt nanoparticles promoted by the cooperation of steric and electronic effects
Liu, Hangyu1,2; Mei, Qingqing1; Li, Shaopeng1,2; Yang, Youdi1,2; Wang, YanYan1,2; Liu, Huizhen1,2; Zheng, LiRong3; An, Pengfei3; Zhang, Jing3; Han, Buxing1,2
刊名Chemical communications
2018-01-25
卷号54期号:8页码:908-911
ISSN号1359-7345
DOI10.1039/c7cc08942b
通讯作者Liu, huizhen(liuhz@iccas.ac.cn) ; Han, buxing(hanbx@iccas.ac.cn)
英文摘要The selective hydrogenation of alpha, beta-unsaturated aldehydes to unsaturated alcohols can reach high selectivity and activity at room temperature using pt nanoparticles immobilized on a non-porous al2o3 support stabilized by aspartic acid. aspartic acid molecules had a significant steric effect on c=c hydrogenation and could modify the electronic state of metal particles.
WOS关键词SECONDARY PHOSPHINE OXIDES ; METAL-ORGANIC FRAMEWORKS ; CHEMOSELECTIVE HYDROGENATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; HIGHLY EFFICIENT ; CINNAMALDEHYDE HYDROGENATION ; CATALYZED HYDROGENATION ; ,-UNSATURATED ALDEHYDES ; RUTHENIUM CATALYSTS ; MILD CONDITIONS
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000423464900010
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2177916
专题高能物理研究所
通讯作者Liu, Huizhen; Han, Buxing
作者单位1.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Inst Chem, CAS Key Lab Colloid & Interface & Thermodynam,Bei, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Liu, Hangyu,Mei, Qingqing,Li, Shaopeng,et al. Selective hydrogenation of unsaturated aldehydes over pt nanoparticles promoted by the cooperation of steric and electronic effects[J]. Chemical communications,2018,54(8):908-911.
APA Liu, Hangyu.,Mei, Qingqing.,Li, Shaopeng.,Yang, Youdi.,Wang, YanYan.,...&Han, Buxing.(2018).Selective hydrogenation of unsaturated aldehydes over pt nanoparticles promoted by the cooperation of steric and electronic effects.Chemical communications,54(8),908-911.
MLA Liu, Hangyu,et al."Selective hydrogenation of unsaturated aldehydes over pt nanoparticles promoted by the cooperation of steric and electronic effects".Chemical communications 54.8(2018):908-911.
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