Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center | |
Xie, Zhen-ni1,2; Mei, Lei2; Wu, Qun-yan2; Hu, Kong-qiu2; Xia, Liang-shu1; Chai, Zhi-fang2,3,4; Shi, Wei-qun2 | |
刊名 | Dalton transactions |
2017-06-21 | |
卷号 | 46期号:23页码:7392-7396 |
ISSN号 | 1477-9226 |
DOI | 10.1039/c7dt01034f |
通讯作者 | Xia, liang-shu(publicxls@163.com) ; Shi, wei-qun(shiwq@ihep.ac.cn) |
英文摘要 | The first reversible solid-state single-crystal-to-single-crystal isomerisation mediated by the change of uranyl-ligand coordination modes, that is from seven-coordinated uranium(vi) of alpha-up to six-coordinated uranium(vi) of the supramolecular isomer, beta-up, has been achieved in the uranyl polyrotaxane system by a temperature-induced strategy. |
WOS关键词 | SOLID-STATE REACTIVITY ; STRUCTURAL TRANSFORMATIONS ; CATALYZED TRANSFORMATION ; SUPRAMOLECULAR INCLUSION ; BASIS-SETS ; POLYMERS ; URANIUM ; DEHYDRATION ; COMPLEXES ; NETWORKS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000403436200003 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2177302 |
专题 | 高能物理研究所 |
通讯作者 | Xia, Liang-shu; Shi, Wei-qun |
作者单位 | 1.Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Hunan, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China 3.Soochow Univ, Sch Radiol & Interdisciplinary Sci, Suzhou 215123, Peoples R China 4.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China |
推荐引用方式 GB/T 7714 | Xie, Zhen-ni,Mei, Lei,Wu, Qun-yan,et al. Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center[J]. Dalton transactions,2017,46(23):7392-7396. |
APA | Xie, Zhen-ni.,Mei, Lei.,Wu, Qun-yan.,Hu, Kong-qiu.,Xia, Liang-shu.,...&Shi, Wei-qun.(2017).Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center.Dalton transactions,46(23),7392-7396. |
MLA | Xie, Zhen-ni,et al."Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center".Dalton transactions 46.23(2017):7392-7396. |
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