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Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center
Xie, Zhen-ni1,2; Mei, Lei2; Wu, Qun-yan2; Hu, Kong-qiu2; Xia, Liang-shu1; Chai, Zhi-fang2,3,4; Shi, Wei-qun2
刊名Dalton transactions
2017-06-21
卷号46期号:23页码:7392-7396
ISSN号1477-9226
DOI10.1039/c7dt01034f
通讯作者Xia, liang-shu(publicxls@163.com) ; Shi, wei-qun(shiwq@ihep.ac.cn)
英文摘要The first reversible solid-state single-crystal-to-single-crystal isomerisation mediated by the change of uranyl-ligand coordination modes, that is from seven-coordinated uranium(vi) of alpha-up to six-coordinated uranium(vi) of the supramolecular isomer, beta-up, has been achieved in the uranyl polyrotaxane system by a temperature-induced strategy.
WOS关键词SOLID-STATE REACTIVITY ; STRUCTURAL TRANSFORMATIONS ; CATALYZED TRANSFORMATION ; SUPRAMOLECULAR INCLUSION ; BASIS-SETS ; POLYMERS ; URANIUM ; DEHYDRATION ; COMPLEXES ; NETWORKS
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000403436200003
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2177302
专题高能物理研究所
通讯作者Xia, Liang-shu; Shi, Wei-qun
作者单位1.Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Hunan, Peoples R China
2.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China
3.Soochow Univ, Sch Radiol & Interdisciplinary Sci, Suzhou 215123, Peoples R China
4.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China
推荐引用方式
GB/T 7714
Xie, Zhen-ni,Mei, Lei,Wu, Qun-yan,et al. Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center[J]. Dalton transactions,2017,46(23):7392-7396.
APA Xie, Zhen-ni.,Mei, Lei.,Wu, Qun-yan.,Hu, Kong-qiu.,Xia, Liang-shu.,...&Shi, Wei-qun.(2017).Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center.Dalton transactions,46(23),7392-7396.
MLA Xie, Zhen-ni,et al."Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center".Dalton transactions 46.23(2017):7392-7396.
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