Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs | |
Zhao, Ran1,2; Mei, Lei1,2; Hu, Kong-qiu1,2; Wang, Lin1,2; Chai, Zhi-fang1,2,3,4; Shi, Wei-qun1,2 | |
刊名 | European journal of inorganic chemistry
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2017-03-17 | |
期号 | 11页码:1472-1477 |
关键词 | Heterometallic complexes Carboxylate ligands Helical structures Actinides Silver |
ISSN号 | 1434-1948 |
DOI | 10.1002/ejic.201601369 |
通讯作者 | Shi, wei-qun(shiwq@ihep.ac.cn) |
英文摘要 | Under hydrothermal conditions, two new 3d actinide- silver (an-ag) heterometallic coordination polymers, namely, [ag(uo2)(2)(mu(2)-oh)(bpdc)(2)(h2o)(2)](n) (1) and [ag3th6(mu(3)-o)(mu(3)-oh)(mu(2)-oh)(6)(bpdc)(6)(no3)(6)center dot h2o](n) (2, h(2)bpdc = 2,2'-bipyridine- 3,3'-dicarboxylic acid), were assembled through a hardsoft recognition strategy. compounds 1 and 2 were character-ized by single-crystal x-ray diffraction, powder x-ray diffraction, and infrared spectroscopy. both compounds are constructed through the bridging of infinite polynuclear an-bpdc chiral helical chains by agi cations. compound 2 represents the first thivagi heterometallic coordination polymer. furthermore, the thermal stability and luminescence properties of 1 were studied. |
WOS关键词 | METAL-ORGANIC FRAMEWORKS ; URANYL-ION COMPLEXES ; CRYSTAL-STRUCTURE ; HYDROTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; POSTSYNTHETIC REARRANGEMENT/METALATION ; BIMETALLIC URANYL ; LIGAND SYNTHESIS ; HYBRID MATERIALS ; 2,2'-BIPYRIDYL-3,3'-DICARBOXYLATE |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000397852200007 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2176727 |
专题 | 高能物理研究所 |
通讯作者 | Shi, Wei-qun |
作者单位 | 1.Chinese Acad Sci, Lab Nucl Energy Chem, Inst High Energy Phys, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Key Lab Biomed Effects Nanomat & Nanosafety, Inst High Energy Phys, Beijing 100049, Peoples R China 3.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, Suzhou 215123, Peoples R China 4.Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Ran,Mei, Lei,Hu, Kong-qiu,et al. Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs[J]. European journal of inorganic chemistry,2017(11):1472-1477. |
APA | Zhao, Ran,Mei, Lei,Hu, Kong-qiu,Wang, Lin,Chai, Zhi-fang,&Shi, Wei-qun.(2017).Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs.European journal of inorganic chemistry(11),1472-1477. |
MLA | Zhao, Ran,et al."Two three-dimensional actinide-silver heterometallic coordination polymers based on 2,2 '-bipyridine-3,3 '-dicarboxylic acid with helical chains containing dimeric or trimeric motifs".European journal of inorganic chemistry .11(2017):1472-1477. |
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