Homogeneous carbon dioxide reduction with p-block element-containing reductants | |
Wu LP(吴立朋) | |
刊名 | Green Chemistry |
2018-12-10 | |
期号 | 20页码:5415-5426 |
关键词 | Homogeneous, Carbon Dioxide, Reduction, P-block Elements |
DOI | 10.1039/C8GC03022G |
英文摘要 | Carbon dioxide is abundant in nature. The reduction of carbon dioxide provides an attractive and alternative method for its utilization as a C1 building block. Compared to molecular hydrogen, carbon dioxide reduction using reductants containing p-block elements (especially E–H) requires much milder reaction conditions and gives diverse products. In this tutorial review, carbon dioxide reduction with various reductants containing p-block elements (E = B, Si, P, Al, Ga, Ge, Sn) other than H2 are discussed and classified by the species in use. Value-added chemicals such as the corresponding formates, acetal, methoxide and methane are produced with the coproduction of “E–O” molecules/polymers. From another perspective, this type of reaction can also be deemed as the oxidation of main group compounds using CO2 as a soft oxidant or CO2mediated dehydrogenative polymerization. We also discussed the preparation route for main group reductants and it is obvious that most of the main group hydrides are expensive to prepare and hard to handle at a large scale, thus work focusing on main group species other than CO2 transformation should be a promising direction. |
URL标识 | 查看原文 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/24809] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Wu LP(吴立朋) |
作者单位 | State Key Laboratory for Oxo Synthesis and Selective Oxidation |
推荐引用方式 GB/T 7714 | Wu LP. Homogeneous carbon dioxide reduction with p-block element-containing reductants[J]. Green Chemistry,2018(20):5415-5426. |
APA | Wu LP.(2018).Homogeneous carbon dioxide reduction with p-block element-containing reductants.Green Chemistry(20),5415-5426. |
MLA | Wu LP."Homogeneous carbon dioxide reduction with p-block element-containing reductants".Green Chemistry .20(2018):5415-5426. |
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