Transition-Metal-Free Reductive Deoxygenative Olefination with CO2

doi:10.1021/acs.orglett.8b01155

	Transition-Metal-Free Reductive Deoxygenative Olefination with CO2
	Zhu Dao-Yong ; Li Wen-Duo ; Yang Ce ; Jie Chen ; Xia Ji-Bao(夏纪宝）; Xia Ji-Bao
刊名	Org. Lett.
	2018-05-15
期号	20 页码:3282−3285
DOI	10.1021/acs.orglett.8b01155
英文摘要	A new transition-metal-free reductive deoxygenative olefination of phosphorus ylides with CO2, an abundant and sustainable C1 chemical feedstock, is described. This catalytic CO2 fixation afforded β-unsubstituted acrylates and vinyl ketones in good yields with broad scope and good functional group tolerance under mild reaction conditions. Cost-effective and easily handled polymethylhydrosiloxane was used as a reductant. Bis(silyl)acetal was proved to be the key intermediate in this reductive functionalization of CO2
URL标识	查看原文
语种	英语
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/24728]
专题	中国科学院兰州化学物理研究所
通讯作者	Xia Ji-Bao(夏纪宝）; Xia Ji-Bao
作者单位	1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 3.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 4.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences 5.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
推荐引用方式 GB/T 7714	Zhu Dao-Yong,Li Wen-Duo,Yang Ce,et al. Transition-Metal-Free Reductive Deoxygenative Olefination with CO2[J]. Org. Lett.,2018(20):3282−3285.
APA	Zhu Dao-Yong,Li Wen-Duo,Yang Ce,Jie Chen,Xia Ji-Bao,&Xia Ji-Bao.(2018).Transition-Metal-Free Reductive Deoxygenative Olefination with CO2.Org. Lett.(20),3282−3285.
MLA	Zhu Dao-Yong,et al."Transition-Metal-Free Reductive Deoxygenative Olefination with CO2".Org. Lett. .20(2018):3282−3285.