Inhibition of CdS photocorrosion by Al2O3 shell for highly stable photocatalytic overall water splitting under visible light irradiation | |
Ning XF(宁晓峰)1,2; Zhen WL(甄文龙)1; Wu YQ(吴玉琪)1; Lu GX(吕功煊)1; Wu YQ(吴玉琪); Lv GX(吕功煊) | |
刊名 | Applied Catalysis B: Environmental |
2018 | |
卷号 | 226期号:0页码:373-383 |
关键词 | Inhibition Of Cds Photocorrosion Inert Al2o3 Shell Visible Light-driven Pt/cds@al2o3 Overall Water Splitting Artificial Gill |
ISSN号 | 0926-3373 |
DOI | 10.1016/j.apcatb.2017.12.067 |
英文摘要 | Efficiency and stability are the two key points for CdS photocatalyst because its application has been seriously restricted owing to serious photocorrosion issue and the recombination of photo-induced charge pairs. In this paper, CdS nanoparticles (NPs) were surface-modified by chemical inert Al2O3 shell. This modification could prevent nascent formed oxygen induced photo-corrosion and enhance the photo-stability of CdS during water splitting significantly. In addition, it was found that such a shell could enhance efficient separation of photo-induced charge pairs. Besides, with the assistance of artificial gill of removing nascent formed O2 from water, Pt/CdS@Al2O3 photocatalyst can achieve overall water splitting under visible light irradiation. The rate of H2 evolution increased 126 times over Pt/CdS@Al2O3 composite compared with pure CdS NPs, and the stability was maintained in several cycles of reaction without any decrease. The measurement of concentration of Cd2+ in solution after long cycles by ICP method confirmed this anti-photo-corrosion property of Al2O3 shell on CdS. This work provides a new potential way to design and fabricate more stable and efficient CdS-based nanocomposite photocatalysts for versatile solar energy conversion. |
学科主题 | 物理化学与绿色催化 |
资助项目 | 环境催化与氢能研究组 |
语种 | 英语 |
WOS记录号 | WOS:000425476800039 |
资助机构 | the NSFC (Grant Nos. 21673262 ; 21433007) |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.ac.cn/handle/362003/23704] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Wu YQ(吴玉琪); Lv GX(吕功煊) |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ning XF,Zhen WL,Wu YQ,et al. Inhibition of CdS photocorrosion by Al2O3 shell for highly stable photocatalytic overall water splitting under visible light irradiation[J]. Applied Catalysis B: Environmental,2018,226(0):373-383. |
APA | Ning XF,Zhen WL,Wu YQ,Lu GX,Wu YQ,&Lv GX.(2018).Inhibition of CdS photocorrosion by Al2O3 shell for highly stable photocatalytic overall water splitting under visible light irradiation.Applied Catalysis B: Environmental,226(0),373-383. |
MLA | Ning XF,et al."Inhibition of CdS photocorrosion by Al2O3 shell for highly stable photocatalytic overall water splitting under visible light irradiation".Applied Catalysis B: Environmental 226.0(2018):373-383. |
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