Superstructures with diverse morphologies and highly ordered fullerene C-60 arrays from 1: 1 and 2: 1 adamantane-C-60 hybrid molecules | |
Li HG(李洪光)1; Li HG(李洪光); Cai MR(蔡美荣)1; Sun XF(孙晓峰)1,4; Liu BY(刘宝勇)1,4; Chen, Mengjun3; Wang, Lin2; Zhou SJ(周升菊)1,4 | |
刊名 | Nanoscale |
2017 | |
卷号 | 9期号:42页码:16375-16385 |
ISSN号 | 2040-3364 |
DOI | 10.1039/c7nr06112a |
英文摘要 | Superstructures from fullerene C60-containing compounds, especially those tethered to rigid functional groups with defined shapes, remain largely unexplored. Being the smallest diamondoid, adamantane (Ad) can be viewed as a promising building block for the construction of well-defined superstructures. Here, we report the syntheses of 1 : 1 (4a) and 2 : 1 (4b) Ad-C60 hybrid molecules, which were then used to construct superstructures in binary solvent mixtures via a modified liquid/liquid interfacial precipitation (LLIP) method using CHCl3 as a good solvent. Typically in the combination of DMSO/CHCl3 with a final concentration (cf) of 1.0 mmol L−1, 4a successively forms spheres, plates, nanoflowers and plicated particles with increasing content of DMSO while 4b forms cuboid blocks and microparticles with hierarchically organized surfaces. Changing from DMSO to other poor solvents including acetone, MeOH and EtOAc leads to variations of the morphology of the superstructures for both 4a and 4b. At the nanometer length scale, 4a and 4b adopt different organizations within the superstructures. While 4a tends to self-organize into lamellae with highly ordered C60 layers, the hexagonal phase is dominant in the superstructures formed by 4b. Wettability tests indicate that films formed by the superstructures of 4a and 4b show anti-wetting properties. Besides the solvent effect, the morphology of the superstructures can be also tuned by concentration. For example, when cf is lowered to 0.5 mmol L−1, a new form of superstructure, i.e., fibers, was detected for 4a. Our results also indicate that besides the solvent-induced aggregate transition, gravity-induced sedimentation and subsequent structure ripening can have a significant influence on the final morphology of the superstructures and the aggregate transition pathways. |
学科主题 | 材料科学与物理化学 |
资助项目 | 柔性有机太阳能电池研究组;材料表面界面研究组 |
语种 | 英语 |
WOS记录号 | WOS:000414349100032 |
资助机构 | National Natural Science Foundation of China (no. 21402215;no. 61474124) |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.ac.cn/handle/362003/22789] |
专题 | 兰州化学物理研究所_清洁能源化学与材料实验室 兰州化学物理研究所_固体润滑国家重点实验室 |
通讯作者 | Li HG(李洪光) |
作者单位 | 1.State Key Laboratory of Solid Lubrication & Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, Gansu Province, 730000, China 2.Analytical Center of Qilu Normal University, Jinan, Shandong Province, 250200, China 3.Key Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials, Shandong University, Ministry of education, Jinan, Shandong Province, 250100, China 4.University of Chinese Academy of Sciences, Beijing, 100049, China |
推荐引用方式 GB/T 7714 | Li HG,Li HG,Cai MR,et al. Superstructures with diverse morphologies and highly ordered fullerene C-60 arrays from 1: 1 and 2: 1 adamantane-C-60 hybrid molecules[J]. Nanoscale,2017,9(42):16375-16385. |
APA | Li HG.,李洪光.,Cai MR.,Sun XF.,Liu BY.,...&Zhou SJ.(2017).Superstructures with diverse morphologies and highly ordered fullerene C-60 arrays from 1: 1 and 2: 1 adamantane-C-60 hybrid molecules.Nanoscale,9(42),16375-16385. |
MLA | Li HG,et al."Superstructures with diverse morphologies and highly ordered fullerene C-60 arrays from 1: 1 and 2: 1 adamantane-C-60 hybrid molecules".Nanoscale 9.42(2017):16375-16385. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论