The role of a metallic copper interlayer during visible photocatalytic hydrogen generation over a Cu/Cu2O/Cu/TiO2 catalyst | |
Wu YQ(吴玉琪)1; Lv GX(吕功煊); Wu YQ(吴玉琪); Lu GX(吕功煊)1,2; Jing, Huanwang2; Jiao, Wenjun1,2; Zhen WL(甄文龙)1 | |
刊名 | Catalysis Science and Technology |
2017 | |
卷号 | 7期号:21页码:5028-5037 |
ISSN号 | 2044-4753 |
DOI | 10.1039/c7cy01432e |
英文摘要 | The role of metallic copper as a co-catalyst is still uncertain, which is an interesting problem in photocatalytic hydrogen evolution. There is debate over the role of Cu+, Cu2+ and metallic Cu during photocatalytic hydrogen generation. Herein, we identified that the metallic copper interlayer between Cu2O and TiO2 played a key role in the hydrogen evolution process. By fabricating the metallic Cu interlayer via in situ reduction of Cu2O/TiO2, efficient charge transfer took place over the Cu/Cu2O/Cu/TiO2 catalyst, while a retarded electron transfer was found over the Cu/TiO2 catalyst. This interlayer structure provides a bridge for photoelectron transfer from th`e conduction band of TiO2 to Cu2O, significantly prolonging the life-time of electron transfer. In addition, the ratio of metallic Cu and Cu2O could be easily adjusted by the loading amount of Cu2O on TiO2, and that the ratio affects the photocatalytic hydrogen evolution activity. A high transient photocurrent and long fluorescence lifetime (0.365 ns) were achieved over the Cu/Cu2O/Cu/TiO2 catalyst when the molar ratio of the interlayer metallic Cu to Cu2O was 0.99. Under the same reaction conditions, the photocatalytic hydrogen generation activity of the Cu/Cu2O/Cu/TiO2 catalyst was three times than that observed with the Cu/TiO2 catalyst with good stability. |
学科主题 | 物理化学与绿色催化 |
资助项目 | 环境催化与氢能研究组 |
语种 | 英语 |
WOS记录号 | WOS:000414041700017 |
资助机构 | the National Natural Science Foundation of China (Grant No. 21433007;21673262) |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.ac.cn/handle/362003/22756] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Lv GX(吕功煊); Wu YQ(吴玉琪); Jing, Huanwang |
作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Univ, Coll Chem & Chem Engn, Expt Chem Teaching Ctr, Lanzhou 730000, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Wu YQ,Lv GX,Wu YQ,et al. The role of a metallic copper interlayer during visible photocatalytic hydrogen generation over a Cu/Cu2O/Cu/TiO2 catalyst[J]. Catalysis Science and Technology,2017,7(21):5028-5037. |
APA | Wu YQ.,吕功煊.,吴玉琪.,Lu GX.,Jing, Huanwang.,...&Zhen WL.(2017).The role of a metallic copper interlayer during visible photocatalytic hydrogen generation over a Cu/Cu2O/Cu/TiO2 catalyst.Catalysis Science and Technology,7(21),5028-5037. |
MLA | Wu YQ,et al."The role of a metallic copper interlayer during visible photocatalytic hydrogen generation over a Cu/Cu2O/Cu/TiO2 catalyst".Catalysis Science and Technology 7.21(2017):5028-5037. |
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