Inorganic adhesives for robust, self-healing, superhydrophobic surfaces
Liu MM(刘明明)1,3; Hou YY(侯媛媛)1,3; Li J(李静)1; Tie L(铁璐)1,3; Peng, Yubing2; Guo ZG(郭志光)1,2; Li J(李静); Guo ZG(郭志光)
刊名Journal of Materials Chemistry A
2017
卷号5期号:36页码:19297-19305
ISSN号2050-7488
DOI10.1039/c7ta06001g
英文摘要

Superhydrophobic surfaces demonstrate remarkable advantages involving interfacial issues but limited practical applications due to their poor mechanical robustness and environmental durability. The required micro-/nano-hierarchical structures and low-surface-energy nanocomponents are very vulnerable to physical and chemical destruction. Moreover, harsh conditions fundamentally weaken the mechanical strength of already-constructed robust superhydrophobic surfaces. In this work, inorganic adhesives are proposed to strengthen the bonding force between superhydrophobic coatings and various substrates. A simple spray-coating method is adopted to fabricate superhydrophobic surfaces using an all-in-one suspension that contains an aluminum phosphate binder, titanium dioxide nanoparticles, and alkylsilane. The surfaces benefitting from inorganic adhesives still extremely repel water after physical abrasion, and greatly endure harsh conditions including hot oil (80 °C), hot water (80 °C), and hot acetone (50 °C) for 24 h to preserve their high mechanical strength. The prepared coatings also have a self-healing ability against boiling-water treatment, O2-plasma etching, and amphiphilic pollution. Superhydrophobicity can be rapidly regenerated after multiple cycles of high-temperature repairing for 5 min. In addition, the robust interfacial materials exhibit a very reliable performance in oil–water separation after 100 abrasion cycles. Benefiting from the distinctive advantages of inorganic adhesives, interfacial materials will be broadly developed for practical applications in related fields.

学科主题材料科学与物理化学
资助项目空间润滑材料研究组
语种英语
WOS记录号WOS:000411232100042
资助机构the National Natural Science Foundation of China (no. 51522510;51675513)
内容类型期刊论文
源URL[http://ir.licp.ac.cn/handle/362003/22493]  
专题兰州化学物理研究所_固体润滑国家重点实验室
通讯作者Li J(李静); Guo ZG(郭志光)
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China
2.Hubei Univ, Key Lab Green Preparat & Applicat Funct Mat, Minist Educ, Wuhan 430062, Hubei, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Liu MM,Hou YY,Li J,et al. Inorganic adhesives for robust, self-healing, superhydrophobic surfaces[J]. Journal of Materials Chemistry A,2017,5(36):19297-19305.
APA Liu MM.,Hou YY.,Li J.,Tie L.,Peng, Yubing.,...&郭志光.(2017).Inorganic adhesives for robust, self-healing, superhydrophobic surfaces.Journal of Materials Chemistry A,5(36),19297-19305.
MLA Liu MM,et al."Inorganic adhesives for robust, self-healing, superhydrophobic surfaces".Journal of Materials Chemistry A 5.36(2017):19297-19305.
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