[Bis(imidazolyl)-BH2](+)[Bis(triazolyl)-BH2](-) Ionic Liquids with High Density and Energy Capacity

doi:10.1002/asia.201800705

	[Bis(imidazolyl)-BH2](+)[Bis(triazolyl)-BH2](-) Ionic Liquids with High Density and Energy Capacity
	Jiao, Nianming 1,2; Zhang, Yanqiang 1; Li, Hao 1,3; Liu, Long 1; Zhang, Suojiang 1
刊名	CHEMISTRY-AN ASIAN JOURNAL
	2018-08-06
卷号	13 期号:15 页码:1932-1940
关键词	Borohydrides Energy Ionic Liquids Nitrogen Heterocycles Propellants
ISSN号	1861-4728
DOI	10.1002/asia.201800705
英文摘要	[Bis(imidazolyl)-BH2](+)[bis(triazolyl)-BH2](-) and [bis(imidazolyl)-BH2](+)[tris(triazolyl)-BH](-) were synthesized, the cations and anions of which were functionalized with B-H groups and azoles. As B-H groups contribute to the hypergolic activity and azole groups improve the energy output, the resulting ionic liquids exhibited ignition delay times as low as 20 ms and energy outputs as high as 461.1 kJ mol(-1). In addition, densities (1.07-1.22 gcm(-3)) and density-specific impulse (approximate to 360 sgcm(-3)) values reached a relatively high level. These ionic liquids show great promise as sustainable rocket fuels.
资助项目	National Key Research and Development Program of China[2016YFB0600903] ; National Natural Science Foundation of China[21576270] ; National Natural Science Foundation of China[21676281] ; Fund of State Key Laboratory of Multiphase Complex Systems, IPE, CAS[MPCS-2015-A-05] ; Key Program of National Natural Science Foundation of China[91434203]
WOS关键词	Ignition-delay Times ; Hypergolic Fuels ; Salts
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000445894800012
资助机构	National Key Research and Development Program of China ; National Natural Science Foundation of China ; Fund of State Key Laboratory of Multiphase Complex Systems, IPE, CAS ; Key Program of National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/26241]
专题	中国科学院过程工程研究所
通讯作者	Zhang, Yanqiang; Zhang, Suojiang
作者单位	1.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.China Univ Petr, Sch Chem Engn, Beijing 102249, Peoples R China
推荐引用方式 GB/T 7714	Jiao, Nianming,Zhang, Yanqiang,Li, Hao,et al. [Bis(imidazolyl)-BH2](+)[Bis(triazolyl)-BH2](-) Ionic Liquids with High Density and Energy Capacity[J]. CHEMISTRY-AN ASIAN JOURNAL,2018,13(15):1932-1940.
APA	Jiao, Nianming,Zhang, Yanqiang,Li, Hao,Liu, Long,&Zhang, Suojiang.(2018).[Bis(imidazolyl)-BH2](+)[Bis(triazolyl)-BH2](-) Ionic Liquids with High Density and Energy Capacity.CHEMISTRY-AN ASIAN JOURNAL,13(15),1932-1940.
MLA	Jiao, Nianming,et al."[Bis(imidazolyl)-BH2](+)[Bis(triazolyl)-BH2](-) Ionic Liquids with High Density and Energy Capacity".CHEMISTRY-AN ASIAN JOURNAL 13.15(2018):1932-1940.